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Acids and Bases
TEKS: 2A, 2B, 2C, 2D, 2E, 3B, 3C, 3D, 3E, <= /span>11A, 11B, 12C, 14A, 14B, 14D
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•List the properties of acids and bases.
•Name an acid or base when given the formula. <= /span>
•Given the hydrogen-ion or hydroxide-ion concentrat= ion, classify a solution as neutral, acidic, or basis.&= #13;
<= span style=3D'font-size:63%'>•Convert hydrogen-ion concentrations into values of= pH and hydroxide-ion concentrations into values of pOH.
•Compare and contrast acids and bases as defined by= the theories of Arrhenius, Bronsted-Lowry, and Lewis.&= #13;
<= span style=3D'font-size:63%'>•Identify conjugate acid-base pairs in acid-base reactions.
•Define strong acids and weak acids
•Calculate an acid dissociation constant (K<= span style=3D'font-size:41%;position:relative;top:.37em;mso-text-raise:-25%'>a<= /span>) from concentration and pH measurements.
•Arrange acids by strength according to their acid = dissociation constants (Ka).
•Arrange bases by strength according to their base = dissociation constants (Kb).
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oooAKKKKACiiigAooooAKKKKACiiigAooooAKKKKACiiigAooooAKKKKACiiigAooooAKKKKACii igAooooAKKKKACiiigAooooA8ip8rZAplBr3D4wQdaWkHWloActW7T/Xiqamrdmf34qZfCy6fxo6 7Tugrdi+7WFp3QVuxfdryqm59Nh/hJqKKKyOoKKKKACiiigAooooAKKKKACiiigAooooAKKKKACi iigAooooAKKKKACiiigAooooAKKKKACiiigAooooAKKKKACiiigAooooAKKKKACiiigAooooAKKK KACiiigAooooAKKKKACiiigAooooAKKKKACiiigD/9k= ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0003.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
Properties of Acids and Bases
•Acids – tart, sour, react with metals to pro= duce H2 gas, reacts with a base to form wa= ter and a salt, strong or w= eak electrolyte, pH paper turns red, pH less than 7
•Bases – bitter, slippery with acid to produc= e water and salt, strong or weak electrolyte, pH paper turns blue, pH greater than 7<= /div>
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Naming Acids
•No oxygen present
<= span style=3D'font-size:71%'>–H2S  hydro_________ic acid
•
•Has oxygen
<= span style=3D'font-size:71%'>–H2SO3<= /span> (sulfite)  __________ous acid
–
<= span style=3D'font-size:71%'>–H2SO4<= /span>  (sulfate) __________ic acid
–
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Naming Acids
•No oxygen present
<= span style=3D'font-size:71%'>–H2S  hydrosulfuric acid
•
•Has oxygen
<= span style=3D'font-size:71%'>–H2SO3<= /span> (sulfite)  sulfurous acid
–
<= span style=3D'font-size:71%'>–H2SO4<= /span>  (sulfate) sulfuric acid
–
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•H20 is = the same as HOH
•
•
–    hydronium ion    hydroxide ion
–
•H20   +   H20   →   H30+<= /span>   +   OH–
•HOH   +   HOH   → &nbs= p; H30+   +   OH̵= 1;
•
•Self-Ionization
•
–H20     →   H+   +   OH̵= 1;
–HOH   <= /span>→   H+<= /span>   +   OH–
–
–   hydrogen ion
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0005_image004.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhKQAcAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAAAj ABcAgAAAAP//zAI3DI6pyxvWomRvWluvdnD7k31bKGpkiXXodK5R63JxOrNqrcA4eO+8T+kBK7rY 4wjkFV3H5apZAAA7 ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0005_image005.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhGAAfAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAUABAAS ABsAgAAAAP//zAItDI6pF73PmoNJTookVsbs5X2VOJKZeaKhuZLt98IoM8ebjeGQvs8AD/IBg6oC ADs= ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0005_image006.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhCgAaAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAMAAAAH ABYAgAAAAP//zAIYhB+HCsmu4Hq0RtawzHZeG4QhIpJSSSoFADs= ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0006.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
Neutral Solution
• [H+]   &   [OH–]   =3D   1.0 x 10-7=
• [H+]   =3D   [OH<= span style=3D'mso-bidi-font-family:Arial;font-size:50%;position:relative;top:-.= 45em; mso-text-raise:30%'>–]
• [H+]   [OH–]   =3D   Kw (water constant)
• [H+]   [OH–]   =3D   1.0 x10-1= 4 (water constant)
• [1.0 x 10-7= ]   [1.0 x 10-7]   =3D   1.0 x 10-1= 4
•
• [H+]  is indirectly proportional to [OH–]
•  H2O
• HCl(g)   → &nbs= p; H+(aq)  +  Cl̵= 1;(aq)
•      H<= /span>20&= #13;
• NaOH(s)   → &nbs= p; Na+(aq)  +   OH̵= 1;(aq)
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&#= 8226; #6  If the hydroxide-ion concentratio= n of an aqueous solution= is 1.0 x 10-3 M.  What is the [H+<= /span>] .  = Is the solution acidic, basic or neutral?
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• #6  If the hydroxide-ion concentratio= n of an aqueous solution is 1.0= x 10-3=  M.  What is the [H+<= /span>] .  = Is the solution acidic, basic or neutral?
•    Kw =3D [H+] [OH–]
•    [H+]  =3D  Kw     = ;      [H= +<= /span>]  = =3D 1.0 x 10-1= 4 =3D = 1.0 x 10-1= 1 mol/= L
•        = ;        [OH–]        = ;             1.0 x 10-3
•
•    = [OH–] 1.0 x 10-3 > [H+] 1.0 x 10-11
•    = Basic
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•#7  C= lassify each solution as acidic or neutral.
R= 11;
–a.   [H+<= /span>]  &nbs= p;  =3D   6.0 x 10-1= 0 M= 3;
–
–
–b.   [OH–] =3D   3.0   x 10-2=  M= 3;
–
–
–c.   [H+<= /span>]  &nbs= p;  =3D   2.0 x 10-7=  M= 3;
–
–
–d.  [= OH–]   =3D   1.0 x 10-7=  M= 3;
R= 11;
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•<= /span>#7  C= lassify each solution as acidic or neutral.
–
–a.   [H+]      =3D   6.0 x 10-1= 0 M= 3;
–      [OH–]   =3D  1.0 x 10-14 =3D<= span style=3D'mso-spacerun:yes'>  1.7 x 10 x 10-5=     
–        = ;            &n= bsp; 6.0 x 10-10
–        = ;            &n= bsp;             6.0 x 10-1= 0 <= 1.7 x 10 x 10-5 ; basic
–b.    [OH–]  =3D  3.0 x 10-2 M
–       [H<= /span>+<= /span>]  &nbs= p;  =3D  1.0 x 10-1= 4 =3D<= span style=3D'mso-spacerun:yes'>  3.3 x 10-13  
–        = ;            &n= bsp;             3.0 x 10-2=
–        = ;            &n= bsp;             3.0 x 10-2= > 3.3 x 10-13 ; ba= sic
–c.    [H+<= /span>]  &nbs= p;  =3D  2.0 x 10-7=  M= 3;
–      [OH–]   =3D  1.0 x 10-14 =3D<= span style=3D'mso-spacerun:yes'>   5.0 x 10-8=   = ;
–        = ;            &n= bsp; 2.0 x 10-7
–        = ;            &n= bsp; 2.0 x 10-7 > 5.0 x 10-8=   ; acidic
–d.  [OH̵= 1;]  &nbs= p; =3D  1.0 x 10-7=  M= 3;
–       [H<= /span>+<= /span>]  &nbs= p;  =3D  1.0 x 10-1= 4 =3D<= span style=3D'mso-spacerun:yes'>  1.0 x 10-7  = ;
–        = ;            &n= bsp; 1.0 x 10-7
–        = ;            &n= bsp;            1.0 x 10-7=     =3D 1.0 x 10-7  ; neutral
–        = ;            &n= bsp;            = ;    
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The pH Concept
<= /v:shape>
•
•pH   =3D   - log [H+<= /span>]
•
•pOH   =3D   - log [OH–]
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•#8  F= ind the pH of each solution.
• a. [H+]   =3D   1.0 x 10-4=  M= 3;
•
•
•
• b. [H+]   =3D   0.0010 M
•
•
•
• c. [H+]   =3D   1.0 10-9=  M= 3;
•
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•#8  Find the pH of each solution. = ;
• a. [H+]   =3D   1.0 x 10-4=   = ;
•        = ;    pH =3D - log [H+] = ;
•        = ;    pH  =3D -log [1.0 x 10= -4=  ]= 3;
•        = ;    pH =3D - [-4.00] =3D 4.00
•
•    b. [H+<= /span>]   =3D   0.0010 M= 3;
•        = ;   pH =3D -log [H+] = ;
•        = ;   pH  =3D  - [0.0010]
•        = ;   pH  =3D -[-3.00]  =3D 3.00
•
•    c. [H+<= /span>]   =3D   1.0 10-9=  M= 3;
•        = ;   pH  =3D - log [H+<= /span>]
•        = ;   pH  =3D  -  log [1.0 10-9 ]
•        = ;   pH  =3D  -[-9.00]  =3D  9.00
•
Two significant fi= gures
2 deci= mals
Two significant figures
Two significant figures
2 decimals
2 decimals
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<= /v:shape>
• #10  Calculate [H+<= /span>] for each solution.
• a. pH   =3D   5.00
•
•
•
• b. pH   =3D   7.00
•
•
•
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<= /v:shape>
• #10  Calculate [H+<= /span>] for each solution.
• a. pH   =3D   5.00
•        = ;   antilog (- 5.00) =3D 1.00 x 10-5 M= 3;
•
•
• b. pH   =3D   7.00
•        = ;   antilog (-7.00)  =3D  1.00 10-7 M= 3;
•
•
•
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<= /v:shape>
• #12   Calcula= te the pH of each solution.
• a. [H+]   =3D   5.0 x 10-6= M
•
•
•
• b. [H+] =3D=    8.3 x 10-1= 0  M
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<= /v:shape>
• #12   Calcula= te the pH of each solution.
• a. [H+]   =3D   5.0 x 10-6= M
•        = ;   pH   =3D  - log [5.0 x 10-6= ]
•        = ;   pH  =3D  5.30
•
•
• b. [H+] =3D=    8.3 x 10-1= 0  M&#= 13;
•        = ;    pH  =3D  - log [8.3 x 10-1= 0]
•        = ;    pH  =3D  9.08
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• #13  Calculate the pH of the following solution.
• a. [OH–]   =3D   4.3 x 10-5=  M
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• #13  Calculate the pH of the following solution.
• a. [OH̵= 1;]   =3D   4.3 x 10-5=  M= 3;
•        = ;   pOH  =3D  - log [OH̵= 1;]
•        = ;   pOH  =3D  4.37
•        = ;   pH  +  pOH  =3D  14.00
•        = ;   pH  =3D  14.00  -  4.37  =3D  9.63
•    or
•        = ;  [H+]  =3D  1.0 x 10-14
•        = ;            &n= bsp;   4.3 x 10-5
•        = ;  [H+]  =3D  2.3 x 10-10
•        = ;  pH  =3D  - log [2.3 x 10–10]
•        = ;  pH  =3D  9.63
•    
•        = ;  
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Arrhenius Acids & Bases
•Arrhenius Acid – H+ producer
•Acids:
–Monoprotic acid   HCl     HCl  → H+<= /span> + Cl= –
–Diprotic acid    H2<= /span>SO4
–Triprotic acid   H3PO4
•
•Arrhenius Base – OH- producer
• Bases:  Ca(OH)2, NaOH
• Ca(OH)2<= /span>  →   Ca   +   2OH̵= 1;
–= 3;
•H atom contains:&= nbsp; 1p+, 1e-<= /span>, 0no
•H+ ion contains: 1p+<= /span>, 0e-, 0n<= /span>o<= span style=3D'mso-spacerun:yes'>         (1 proton)=
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•
•
•<= /span>Acetic Acid can be written in two forms.
HC2H3O2<= /span> = 211; monoprotic acid – acetic acid
CH3COOH – acetic acid – organic acid = ;
= 3;
H    O
H – C – C – OH
H   
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• #14  What is the molarity of [H= +<= /span>] in each solution.
• a pH  =3D<= span style=3D'mso-spacerun:yes'>  7.30
•
•
•
• b. pH  =3D<= span style=3D'mso-spacerun:yes'>  1.80
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• #14  What is the molarity of [H= +<= /span>] in each solution.
• a pH  =3D<= span style=3D'mso-spacerun:yes'>  7.30
•        = ;   antilog  [-7.30]  =3D  5.0 x 10–8 M
•        = ;   [H+]  =3D 5.0 x 10–8 M
•
•
• b. pH  =3D  1.80
•        = ;   antilog  [-1.80]  =3D 1.6 x 10–2 M
•        = ;   [H+]  =3D 1.6 x 10–2 M
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• #15  Calculate the value of [OH= –] in each = = solution in problem #14.
• a. pH  =3D<= span style=3D'mso-spacerun:yes'>  7.30
•
•
•
• b. pH  =3D<= span style=3D'mso-spacerun:yes'>  1.80
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• #15  Calculate the value of [OH= –] in each = = solution in problem #14.
• a. pH      =3D  7.30
•        = ;   pOH   =3D  14.00 – 7.30  =3D  6.70
•        = ;   [OH–]  =3D=   antilog (-6.70 )
•        = ;   [OH–]  = =3D  2.0 x 10̵= 1;7<= /span> M= 3;
•
• b. pH    =3D  1.80 <= /div>
•        = ;  pOH  =3D  14.00 – 1.80  =3D  12.20
•        = ;  [OH–]  = =3D  antilog (–12.20)= 3;
•        = ;  [OH–]  = =3D  6.3 x 10 -13 M= 3;
•
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Bronsted-Lowry Acids & Bases
• Acid – hydrogen ion (H<= /span>+<= /span>) donor
• Base – hydrogen ion (H<= /span>+<= /span>) acceptor
•
•             = ;HOH
• NH3   +   H2<= /span>O   →   NH4+   +   OH̵= 1;
•
•
•=
• HOH
•= HNO3   +   H2O   →   H3O+   +   NO3–
•
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Bronsted-Lowry Acids & Bases
• Acid – hydrogen ion (H<= /span>+<= /span>) donor
• Base – hydrogen ion (H<= /span>+<= /span>) acceptor
•
•             = ;HOH
• NH3   +   H2<= /span>O   →   NH4+   +   OH̵= 1;
•
•
•=
• HOH
•= HNO3   +   H2O   →   H3O+<= /span>   +   NO3<= /span>–
•
Water donates a H+ to NH3
HNO3 donates H+ to water
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Lewis Acids & Bases
•Acid ̵= 1; electron acceptor
•Base ̵= 1; electron donor
•
•H+<= /span>   +   OH–     →   HOH  (H2<= /span>O)
• Draw electron dot picture for this reaction.&n= bsp; Why?
•
•
•
•
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Lewis Acids & Bases
•Acid – electron acceptor <= /div>
•Base – electron donor
•
•H+   +   OH̵= 1;    →   HOH  (H2<= /span>O)
• Draw electron dot picture fo= r this reaction.  Why?
•    [H]+  +  [  O   H]̵= 1;   →    O   H
•        = ;            &n= bsp;            = ;        H
•
•
•
OH– ion donates an electron to H+ ion
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Amphoteric Substance
<= /v:shape>
•Amphoteric Substance can act as an acid or = base.
•
• H2O   + H2<= /span>O   →   H3O+   +   OH̵= 1;
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Amphoteric Substance
<= /v:shape>
•Amphoteric Substance can act as an acid or = base.
•
• H2O   + H2<= /span>O   →   H3O+   +   OH̵= 1;
•
•     One water molecule donates a H+<= /span> ion = and the other water molecules accepts the H+ = ion.
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• #20  Identify the Lewis acid and Lewis= base in each reaction.  Draw electron dot pictures. <= /span>
•   
• a. H+   +   O   →   H3O+
•        = ;           H     H=
•
•
•
• b. AlCl3   +   Cl̵= 1; →   AlCl4–
•
•
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0021_image033.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhIQALAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAAAAAAf AAkAgAAAAP//zAIchG+Bi8oPHFxyRvtqxlA3PnkXGFIkJomnqa5UAQA7 ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0021_image034.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhHQALAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAAAAAAb AAoAgAAAAP//zAImhB+nG7nc3ANRvmoVzqhO6n1gI4YdSYlTNKIqtLnvuc2Xx9owUAAAOw== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0040.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• #20  Identify the Lewis acid and Lewis= base in each reaction.  Draw electron dot pictures. <= /span>
•   
• a. H+   +   O   →   H3O+
•        = ;           H     H=
•
•        = ;   H+     &n= bsp; O     &nb= sp; →       H  O  H
•        = ;           H     H=         = ;          H        = ;            
•
• b. AlCl3   +   Cl– →   &= nbsp; AlCl4–
•        = ;     Cl        = ;            &n= bsp;         Cl
•       Cl<= span style=3D'mso-spacerun:yes'>  Al  Cl +   Cl     →  Cl<= span style=3D'mso-spacerun:yes'>  Al  Cl
•        = ;            &n= bsp;            = ;             Cl        = ;   
•=
•
H2O donate an electr= on to H+ ion
+
–
–
Cl– ion donates two electrons to AlCl3
Base – H2O
Acid – H+
Base – Cl–=
Acid – AlCl3
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Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhDAA8AHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAAAJ ADwAgAAAAP//zAI+hB+JydYbzpKIVgsi1pZTL4FXh2Wl6JzqtpLs68ZfO8O1HNK5vePjDewFf8Ii 8ZjiIU3KpM+BykQZKGo1UAAAOw== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0040_image058.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhEAA8AHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAIAAAAO ADwAgAAAAP//zAJOjAOpe20Lk4uxUfguQ1rynoGfFpLjVaInlbJr9WLx1nk10MJ3Lu+zwqPVgsCf bWjEJYlHke+JhDqj1KnVJMVWtVdV1rsFd3WmluNzNicLADs= ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0040_image059.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhMAA9AHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAAAAAAv ADwAgAAAAP//zAKahA+hyO0K3YNLWkSzjbd3fXDe+FVJQKZeharuJr5yGM8yZed4Pu/86/upgkIS sbiqIUumZbLpvByjEyi12rrCrFqMskvjgk9i8HR8Nn/Ra3W5m4a35W9t3D7H1693ft6/R9Un+EcY GDWIWKh46JTouAjZuPRIGWk5iVSpecmZWbQJipI1hmHwycOCegMVOpJBGtbJALu4erpXAAA7 ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0022.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
•Strong Acids -&nb= sp; HCL,  H2<= /span>SO4,  HNO3
•Strong Bases – NaOH, KOH, Ca(OH)2&= #13;
•
• Strong Acid
• HCl   →   H+   +   Cl–
• 0%   100%
•
• Weak Acid
• HC2<= /span>H3O2<= /span>    →   H+   +   C2H3O2<= /span>–
• 99% 1%
•
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<= /v:shape>
•HC2H3<= /span>O2    +   H2O   →   H3O+<= /span>   +   C2<= /span>H3O2<= /span>–
•
• Keq equi= librium expression
•
• Keq  =3D=   
•
•
•
• Ka Acid Dissociation Constant expression
•
• Ka<= /span>   =3D
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<= /v:shape>
<= span style=3D'font-size:75%'>•HC<= span style=3D'font-size:50%;position:relative;top:.37em;mso-text-raise:-25%'>2<= /span>H3O2<= /span>    +   H2<= /span>O   →   H3O+<= /span>   +   C2<= /span>H3O2<= /span>–
•= 3;
• Keq=  equi= librium expression
•
• Keq=   =3D=    [H3O+] [C<= /span>2<= /span>H3O2<= /span>–]
•        = ;        [HC2H3<= /span>O2] [H<= /span>2<= /span>O]
•= 3;
•= 3;
• Ka<= /span> Acid Dissociation Constant expression
•
• Ka<= /span>   =3D [H3<= /span>O+] [C<= /span>2<= /span>H3O2<= /span>–]
•        = ;       [HC2H3<= /span>O2]
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•Base Dissociation Constant
•
• NH3   +   H2<= /span>O   →   NH4<= /span>+<= /span>   +   OH–
•
•
• Kb   =3D 
•
•
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•Base Dissociation Constant
•
• NH3   +   H2<= /span>O   →   NH4<= /span>+<= /span>   +   OH–
•
•
• Kb   =3D  [NH4<= /span>+<= /span>] [OH–]
•        = ;          [NH3]
•
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<= /v:shape>
•Sample problem 20.8
• A 0.1000 M solution of ethan= oic acid is only parti= ally ionized.  From the measuremen= ts of the pH of the soluti= on [H+<= /span>] is determined to be     <= span style=3D'position:absolute;top:60.37%;left:4.18%;width:90.79%;height:19.81= %'>1.34 x 10-3 M.  What is the Ka of ethanoic acid (acetic acid).
•
•R HC2<= /span>H3O2<= /span>    →   H+   +   C2H3O2<= /span>–
•I
•C
•E
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<= /v:shape>
•Sample pro= blem 20.8
• A 0.1000 M solution of ethanoic acid is only partially ionized.  From the measurements of the pH of the solution [H+] is determined to be     1.34 x 10= -3=  M.  What is the Ka<= /span> of e= thanoic acid (acetic acid).&#= 13;
•= 3;
•R HC2<= /span>H3O2<= /span>    →    H+     +        = ;    C2H3<= /span>O2– = ;
•I        = ;   0.1000        = ;       0        = ;            &n= bsp;  0
•C         -1.34 x 10-3      +1.34 x 1= 0-3=       1.34 x 10= -3=
•E   0.1000-1.34 x 10-3    1.34 x 10-3        1.34 x 10-3
•   = ;  Ka  =3D  [H+] [C2<= /span>H3O2<= /span>–]   
•        = ;         [HC2H3<= /span>O2] = ;
•   = ;  Ka =3D [1.34 x 10-3= ] [1.34 x 10-3] =3D  1.82 x 10-5
•        = ;        [0.1000 - 1.34 x 10-3 ]
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0043_image067.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhUQEDAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAAAAABP AQEAgAAAAP//zAIXjI+py+0PH5i02nuj3rz7hIXi9JXmGRUAOx== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0043_image068.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhewADAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAQB4 AAIAgAAAAP//zAINjI+py+0Po5y02otzKwA7 ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0043_image069.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhywADAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAEAAADJ AAIAgAAAAP//zAIRjI+py+0Po5y02ouz3rz7zxUAOx== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0026.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• #27&= nbsp; For a solution of a monoprotic weak acid exactly 0.200 M, [H+]  = =3D  9.86 x 10-4 M.&#= 13;
• a.  What is the pH of this solution?&= #13;
• b. What is the value of Ka for this acid?
•
•R HA    →   H+   +   A̵= 1;
•I <= /span>
•C
•E
•
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0026_image070.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhvQACAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAAAAAAB AAEAgAAAAAECAwICRAEAOw== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0044.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• #27  For a solution of a monoprotic we= ak acid exactly 0.200 M,= [H+<= /span>]  = =3D  9.86 x 10-4 M.&#= 13;
• a.  What is the pH of this solution?&= #13;
• b. What is the value of Ka for this acid?
•= 3;
•R HA        = ;   →         H+        = ;    +     &nb= sp; A–
•I         0.200        = ;            0        = ;            &n= bsp;   0
•C       -9.= 86 x 10–4          = ;+9.86 x 10–4    +9.86 x 10–4<= /span>  = ;
•E   0.200 - 9.86 x 10–4<= /span>   = ;  9.86 x 10–4<= span style=3D'mso-spacerun:yes'>        9.86= x 10–4 
•Ka  =3D   [9.86 x 10–4 ] [9= .86 x 10–4 ]
•        = ;   [0.200 - 9.86 x 10–4<= /span> ]= 3;
•Ka  =3D   4.89 x 10-6=
•pH  = =3D  -log (H+)  = =3D  - log [9.86 x 10-4= ]
•pH  = =3D  3.006
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&#= 8226; A 0.025 M solution of KHCrO4 has a pH of 3.50.  Calculate the Ka for = the equilibrium between HCrO4<= /span>-<= /span>  and= CrO4<= /span>2-=  .
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0045.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• A 0.025 M solution of KHCrO4 has a pH of 3.50.  Calculate the Ka for = the equilibrium between HCrO<= /span>4<= /span>-<= /span>  and= CrO4<= /span>2-=  .= 3;
•   [H+<= /span>} =3D  antilog (-3.50)  =3D  3.16 x 10-4
•R  &nbs= p;  KHCrO4       →       K+<= /span>        = ;           HCrO4–
•I      0.025        = ;            &n= bsp;   0        = ;            0
•C  &nbs= p; -3.16 x 10-4        = ;           +3.16 x 10-4=      +3.16 x 10-4
•E  &nbs= p; 0.025 - 3.16 x 10-4     3.16= x 10-4=          3.16 x 10-4=
•  Ka<= /span> =3D<= span style=3D'mso-spacerun:yes'>   [K+] [HCrO4– ]
•        = ;    [KHCrO4]
•  Ka<= /span> =3D<= span style=3D'mso-spacerun:yes'>  [3.16 x 10-4= ] [3.16 x 10-4 ]
•        = ;       [0.025 - 3.16 x 10-4 ]&#= 13;
•  Ka<= /span> =3D<= span style=3D'mso-spacerun:yes'>  4.0 x 10-6
•= 3;
•  
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&#= 8226; You have determined that 1.40% of a 0.080 M solution of a weak acid is ionized.  Calculate the Ka for this acid.
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0046.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• You have determined that 1.4= 0% of a 0.080 M solution of a we= ak acid is ionized.  Calculate t= he Ka<= /span> for = this acid.  1.40% =3D  0.0140 =
•    0.080 M x 0.0140 =3D 1.12 x 10-3
•R      HA        →        = ;     H+        = ;     +        = ;      A– 
•I       0.800        = ;            &n= bsp; 0        = ;            &n= bsp;          0
•C  &nbs= p;  = 211;1.12 x 10-3        = ;  +1.12 x 10-3        = ;             +1.12 x 10-3=
•E    0.800 - 1.12 x 10-3     1.12 x 10-3        = ;            &n= bsp;   1.12 x 10-3=
•     Ka<= /span> =3D = [1.12 x 10-3= ] [1.12 x 10-3]
•        = ;    [0.800 - 1.12 x 10-3 ]&#= 13;
•    Ka<= /span>  =3D= 1.6 x 10–5
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• Problem using x
• A solution of a 1.0 M hydrosulfuric acid ionizes in water.  What is the concentration of the = [H+<= /span>] and [S2-= ] ?
------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/slide0047.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template
• Problem using x
• A solution of a 1.0 M hydrosulfuric acid ionizes in water.  What is the concentration of the = [H+<= /span>] and [S2-= ] ?   <= /span>Ka for H2S ;=3D  1.8 x 10-5= 3;
•  R    H2<= /span>S  &nbs= p; →     2H+   +   S2R= 11;
•  I     1.00        = ;     0        = ;    0
•  C    -x        = ;       +2x        +x
•  E    1.00-x         2x     &n= bsp;     x
•   1.8 x = 10-5   =3D    [2x]2  [x]
•        = ;            &n= bsp;     [1.00 – x]
•   4x3  =3D  1.8 x 10-5;   x3  =3D  4.5 x 10-6;   x =3D 0.75 M
•   x   =3D  [S2-]  =3D  .75 M
•   2x =3D=   [2H+] =3D 1.50 M 
You can cancel= xs added or subtracted from numbers only.   Important!!!!
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Content-Transfer-Encoding: quoted-printable Content-Type: application/javascript; charset="us-ascii" function LoadSld() { var sld=3DGetObj("SlideObj") if( !g_supportsPPTHTML ) { =09 sld.style.visibility=3D"visible" return } if( MakeNotesVis() ) return runAnimations =3D _InitAnimations(); =09 if( IsWin("PPTSld") ) parent.SldUpdated(GetSldId()) g_origSz=3DparseInt(SlideObj.style.fontSize) g_origH=3Dsld.style.posHeight g_origW=3Dsld.style.posWidth g_scaleHyperlinks=3D(document.all.tags("AREA").length>0) if( g_scaleHyperlinks ) InitHLinkArray() if( g_scaleInFrame||(IsWin("PPTSld") && parent.IsFullScrMode() ) ) document.body.scroll=3D"no" _RSW() if( IsWin("PPTSld") && parent.IsFullScrMode() ) FullScrInit(); =09 MakeSldVis(); ChkAutoAdv() if( runAnimations ) { if( document.all("NSPlay") ) document.all("NSPlay").autoStart =3D false; if( sld.filters && sld.filters.revealtrans ) setTimeout( "document.body.start()", sld.filters.revealtrans.duration * = 1000 ); else document.body.start(); } } function MakeSldVis()=20 { var fTrans=3Dg_showAnimation && SldHasTrans() if( fTrans )=09 { if( g_bgSound ) { idx=3Dg_bgSound.indexOf(","); pptSound.src=3Dg_bgSound.substr( 0, idx ); pptSound.loop=3D -(parseInt(g_bgSound.substr(idx+1))); } SlideObj.filters.revealtrans.Apply()=09 } SlideObj.style.visibility=3D"visible" if( fTrans ) SlideObj.filters.revealtrans.Play() } function MakeNotesVis()=20 { if( !IsNts() ) return false=20 SlideObj.style.display=3D"none" nObj =3D document.all.item("NotesObj") parent.SetHasNts(0) if( nObj ) {=20 nObj.style.display=3D"" parent.SetHasNts(1) } return 1 } function ChkAutoAdv() { if(SldHasTrans()) SlideObj.onfilterchange=3DAutoAdv else AutoAdv() } function AutoAdv() { if(!IsWin("PPTSld") || !gUseSldTimings )return var sld=3DGetCurSld() if( (sld.mAdvDelay>0) && !parent.IsFramesMode() ) setTimeout("parent.GoToNextSld()",sld.mAdvDelay) } function GetObj(id) { if(g_supportsPPTHTML) return document.all(id); else return document.getElementById(id); } function SldHasTrans() { return SlideObj.style.filter !=3D ""; } function GetSldId() { return sId=3Dlocation.href.substring(location.href.la= stIndexOf('/')+1) } function HideMenu() { if( frames["PPTSld"] && PPTSld.document.all.item("ctx= tmenu") && PPTSld.ctxtmenu.style.display!=3D"none" ) { PPTSld.ctxtmenu.styl= e.display=3D'none'; return true } return false } function IsWin( name ) { return window.name =3D=3D name } function IsNts() { return IsWin("PPTNts") } function IsSldOrNts() { return( IsWin("PPTSld")||IsWin("PPTNts") ) } function SupportsPPTAnimation() { return( navigator.platform =3D=3D "Win32"= && navigator.appVersion.indexOf("Windows")>0 ) } function SupportsPPTHTML() { var appVer=3Dnavigator.appVersion, msie=3DappVer.indexOf("MSIE "), ver=3D0 if( msie >=3D 0 ) ver=3DparseFloat( appVer.substring( msie+5, appVer.indexOf(";",msie) ) ) else ver=3DparseInt(appVer) return( ver >=3D 4 && msie >=3D 0 ) } function _RSW() { if( !g_supportsPPTHTML || IsNts() || ( !g_scaleInFrame && (!IsWin("PPTSld") || !parent.IsFullScrMode()) ) ) return var padding=3D0; if( IsWin("PPTSld") && parent.IsFramesMode() ) padding=3D6 cltWidth=3Ddocument.body.clientWidth-padding cltHeight=3Ddocument.body.clientHeight-padding factor=3D(1.0*cltWidth)/g_origW if( cltHeight < g_origH*factor ) factor=3D(1.0*cltHeight)/g_origH newSize =3D g_origSz * factor if( newSize < 1 ) newSize=3D1 s=3DSlideObj.style s.fontSize=3DnewSize+"px" s.posWidth=3Dg_origW*factor s.posHeight=3Dg_origH*factor s.posLeft=3D(cltWidth-s.posWidth+padding)/2 s.posTop=3D(cltHeight-s.posHeight+padding)/2 if( g_scaleHyperlinks ) ScaleHyperlinks( factor ) } function _InitAnimations() { animRuntimeInstalled =3D ''+document.body.localTime !=3D 'undefined'; isFullScreen =3D (window.name =3D=3D "PPTSld") && !parent.IsFramesMode(); g_animUseRuntime =3D g_showAnimation && animRuntimeInstalled && !(isFullSc= reen && parent.IsSldVisited()); if( g_animUseRuntime ) { collSeq =3D document.all.tags("seq"); if( collSeq !=3D null ) { for(ii=3D0;ii numSlds ) gSldJumpIdx =3D numSlds; if ( gSldJumpIdx >=3D 0 ) { if ( gSldJumpIdx =3D=3D 0 ) gSldJumpIdx =3D 1; var jumpTo =3D parseInt(gSldJumpIdx); gSldJump =3D 0; gSldJumpIdx =3D ""; win.GoToSld( parent.GetSldList().mList[jumpTo-1].mSldHref ) } } } function _KDH() { if( event.keyCode =3D=3D 8 ) { event.returnValue =3D 0; parent.GoToPrevSld(); } } var g_HLinkArray =3D new Array(); =20 function IMapAreaObj( areaObj, coords ) { this.areaObj =3D areaObj; this.coords =3D coords; } function InitHLinkArray() { var appVer =3D navigator.appVersion; var msie =3D appVer.indexOf ( "MSIE " ) var ver =3D 0; if ( msie >=3D 0 ) ver =3D parseInt ( appVer.substring( msie+5 ) ); linkNum =3D 0; for (i=3D0; i 4 ) ) g_HLinkArray[linkNum++] =3D new IMapAreaObj( areaObj, ParseCoords( ar= eaObj.coords ) ); } } function ScaleHyperlinks( factor ) { =20 for ( ii=3D0; ii< g_HLinkArray.length; ii++) { coordsStr=3D""; imaObj =3D g_HLinkArray[ii]; for ( jj=3D0; jj < imaObj.coords.length-1; jj++ ) coordsStr +=3D (imaObj.coords[jj]*factor) + ","; coordsStr +=3D (imaObj.coords[jj]*factor); imaObj.areaObj.coords =3D coordsStr; } } function ParseCoords( coordsStr ) { var numArray =3D new Array(); var i =3D curPos =3D commaPos =3D 0; while ( ( commaPos =3D coordsStr.indexOf(",", curPos) ) !=3D -1 ) {=20 numArray[i++] =3D parseInt( coordsStr.substr( curPos, commaPos ) ); curPos =3D commaPos + 1; } numArray[i] =3D parseInt( coordsStr.substr( curPos ) ); return numArray; } function PlaySound( href, loop ){ href=3D unescape(href); if( window.event ) window.event.cancelBubble =3D true; pptSound.src =3D href; pptSound.loop =3D loop ? -1 : 0; } function DocumentOnClick() { if( IsNts() || parent.HideMenu() ) return; if( ( g_allowAdvOnClick && (window.name=3D=3D"PPTSld") && !parent.IsFrames= Mode() ) || (event && event.keyCode=3D=3D32) ) { =09 if( g_animUseRuntime && g_animMainSequence && g_animMainSequence.cangonex= t ) return; parent.GoToNextSld(); } } var g_supportsPPTHTML =3D SupportsPPTHTML(), g_scaleInFrame =3D 1, gId=3D""= , g_bgSound=3D"", g_scaleHyperlinks =3D false, g_allowAdvOnClick =3D 1, g_showInBrowser = =3D 0, gLoopCont =3D 0, gUseSldTimings =3D 1; var g_showAnimation =3D g_supportsPPTHTML && SupportsPPTAnimation() && ( (w= indow.name=3D=3D"PPTSld" && !parent.IsFramesMode()) || g_showInBrowser );va= r g_animManager =3D null; var g_animUseRuntime =3D false; var g_animItemsToHide, g_animInteractiveItems, g_animSlideTime; var g_animMainSequence =3D null; var ENDSHOW_MESG=3D"End of slide show, click to exit.", SCREEN_MODE=3D"Fram= es", gIsEndShow=3D0, NUM_VIS_SLDS=3D49, SCRIPT_HREF=3D"script.js", FULLSCR_= HREF=3D"fullscreen.htm"; var gCurSld =3D gPrevSld =3D 1, g_offset =3D 0, gNtsOpen =3D gHasNts =3D gO= tlTxtExp =3D 0, gHasNarration =3D 0, gOtlOpen =3D true window.gPPTHTML=3DSupportsPPTHTML() var gMainDoc=3Dnew Array(new hrefList("slide0001.htm",1,-1,1),new hrefList(= "slide0002.htm",1,-1,1),new hrefList("slide0003.htm",1,-1,1),new hrefList("= slide0004.htm",1,-1,1),new hrefList("slide0030.htm",1,-1,1),new hrefList("s= lide0005.htm",1,-1,1),new hrefList("slide0006.htm",1,-1,1),new hrefList("sl= ide0007.htm",1,-1,1),new hrefList("slide0031.htm",1,-1,1),new hrefList("sli= de0008.htm",1,-1,1),new hrefList("slide0032.htm",1,-1,1),new hrefList("slid= e0009.htm",1,-1,1),new hrefList("slide0010.htm",1,-1,1),new hrefList("slide= 0033.htm",1,-1,1),new hrefList("slide0011.htm",1,-1,1),new hrefList("slide0= 034.htm",1,-1,1),new hrefList("slide0012.htm",1,-1,1),new hrefList("slide00= 35.htm",1,-1,1),new hrefList("slide0013.htm",1,-1,1),new hrefList("slide003= 6.htm",1,-1,1),new hrefList("slide0014.htm",1,-1,1),new hrefList("slide0015= .htm",1,-1,1),new hrefList("slide0016.htm",1,-1,1),new hrefList("slide0037.= htm",1,-1,1),new hrefList("slide0017.htm",1,-1,1),new hrefList("slide0038.h= tm",1,-1,1),new hrefList("slide0018.htm",1,-1,1),new hrefList("slide0048.ht= m",1,-1,1),new hrefList("slide0019.htm",1,-1,1),new hrefList("slide0039.htm= ",1,-1,1),new hrefList("slide0020.htm",1,-1,1),new hrefList("slide0049.htm"= ,1,-1,1),new hrefList("slide0021.htm",1,-1,1),new hrefList("slide0040.htm",= 1,-1,1),new hrefList("slide0022.htm",1,-1,1),new hrefList("slide0023.htm",1= ,-1,1),new hrefList("slide0041.htm",1,-1,1),new hrefList("slide0024.htm",1,= -1,1),new hrefList("slide0042.htm",1,-1,1),new hrefList("slide0025.htm",1,-= 1,1),new hrefList("slide0043.htm",1,-1,1),new hrefList("slide0026.htm",1,-1= ,1),new hrefList("slide0044.htm",1,-1,1),new hrefList("slide0027.htm",1,-1,= 1),new hrefList("slide0045.htm",1,-1,1),new hrefList("slide0028.htm",1,-1,1= ),new hrefList("slide0046.htm",1,-1,1),new hrefList("slide0029.htm",1,-1,1)= ,new hrefList("slide0047.htm",1,-1,1)); /********************************************* Frameset functions These functions control slide navigation and state of the frameset. **********************************************/ function FullScrInit() { g_allowAdvOnClick =3D GetCurSld().mAdvOnClk document.body.style.backgroundColor=3D"black" document.oncontextmenu=3Dparent._CM; document.onkeydown =3D _KDH; document.ondragstart=3DCancel document.onselectstart=3DCancel self.focus() } function Redirect( frmId ) {=09 var str=3Ddocument.location.hash,idx=3Dstr.indexOf('#'), sId=3DGetSldId() if(idx>=3D0) str=3Dstr.substr(1); if( window.name !=3D frmId && ( sId !=3D str) ) { obj =3D GetObj("Main-File") window.location.href=3Dobj.href+"#"+sId return 1 } return 0 } var MHTMLPrefix =3D CalculateMHTMLPrefix();=20 function CalculateMHTMLPrefix() { if ( document.location.protocol =3D=3D 'mhtml:') {=20 href=3Dnew String(document.location.href)=20 Start=3Dhref.indexOf('!')+1=20 End=3Dhref.lastIndexOf('/')+1=20 if (End < Start)=20 return href.substring(0, Start)=20 else=20 return href.substring(0, End)=20 } return ''; } function GetTags(base,tag) { if(g_supportsPPTHTML) return base.all.tags(tag); else return base.getElementsByTagName(tag); } function UpdNtsPane(){ if(frames["PPTNts"]) PPTNts.location.replace( MHTMLP= refix+GetHrefObj( gCurSld ).mNtsHref ) } function UpdNavPane( sldIndex ){ if(gNavLoaded) PPTNav.UpdNav() } function UpdOtNavPane(){ if(gOtlNavLoaded) PPTOtlNav.UpdOtlNav() } function UpdOtlPane(){ if(gOtlLoaded) PPTOtl.UpdOtl() } function SetHasNts( fVal ) { if( gHasNts !=3D fVal ) { gHasNts=3DfVal UpdNavPane() } } function ToggleOtlText() { gOtlTxtExp=3D!gOtlTxtExp UpdOtlPane() } function ClearMedia() { // Clear any sounds playing before launching another browser window. Other= wise, // in fullscreen mode, you'll continue to hear the sound in the frames mod= e. if (PPTSld.pptSound) PPTSld.pptSound.loop =3D 0; } function FullScreen() {=20 if ( PPTSld.g_animUseRuntime ) PPTSld.document.body.pause(); ClearMedia(); var href =3D ( document.location.protocol =3D=3D 'mhtml:') ? FULLSCR_HREF = : FULLSCR_HREF+"#"+GetHrefObj(gCurSld).mSldHref; if(PPTNav.event.ctrlKey) { var w =3D (window.screen.availWidth * 1.0) / 2.0 var h =3D w * (PPTSld.g_origH * 1.0) / PPTSld.g_origW win =3D window.open( MHTMLPrefix+href,null,"toolbar=3D0,resizable=3D1,top= =3D0,left=3D0," + "width=3D"+ w + ",height=3D" + h ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } else { win =3D window.open( MHTMLPrefix+href,null,"fullscreen=3Dyes" ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } } function ToggleVNarration() { rObj=3DPPTSld.document.all("NSPlay") if( rObj && !PPTSld.g_animUseRuntime ) { if( (rObj.playState =3D=3D 1)||(rObj.playState =3D=3D 0) ) rObj.Play() else if( rObj.playState =3D=3D 2 ) rObj.Pause() else return; } else if( PPTSld.g_animUseRuntime ) { narObj =3D PPTSld.document.all("narrationID") if( narObj ) narObj.togglePause() } } function GetCurSldNum() { =20 obj=3DGetHrefObj(gCurSld) if( obj.mOrigVis =3D=3D 1 ) return obj.mSldIdx else =20 return gCurSld } function GetNumSlds() { =20 if( GetHrefObj(gCurSld).mOrigVis =3D=3D 1 ) return GetSldList().mNumVisSlds; else return GetSldList().mList.length } function GetSldNum( href ) { for(ii=3D0; ii 1 ) PopSldList(); else if( !IsFramesMode() ) { if( gLoopCont ) GoToFirst() else EndShow() } } function GoToPrevSld() { ii=3DgCurSld-1 if( ii > 0 ) { obj=3DGetHrefObj(ii) while ( obj && ( obj.mVis =3D=3D 0 ) && ( ii>0 ) ) obj=3DGetHrefObj(--ii) if( ii =3D=3D 0 ) ii=3D1 GoToSldNum(ii) } } function GoToFirst(){ GoToSld( GetHrefObj(1).mSldHref ) } function GoToLast() { ii=3DGetSldList().mList.length if( ii !=3D gCurSld ) GoToSld( GetHrefObj(ii).mSldHref ) } function GoToSldNum( num ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue obj =3D GetHrefObj( num ) obj.mVis=3D1 gPrevSld=3DgCurSld gCurSld =3D num; PPTSld.location.replace(MHTMLPrefix+obj.mSldHref) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function GoToSld( href ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue GetHrefObj( GetSldNum(href) ).mVis=3D1 PPTSld.location.replace(MHTMLPrefix+href) } function SldUpdated( id ) { if( id =3D=3D GetHrefObj(gCurSld).mSldHref ) return gPrevSld=3DgCurSld gCurSld=3DGetSldNum(id) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function PrevSldViewed(){ GoToSld( GetHrefObj(gPrevSld).mSldHref ) } function HasPrevSld() { return ( gIsEndShow || ( gCurSld !=3D 1 && GetHrefO= bj( gCurSld-1 ).mVis =3D=3D 1 )||( GetCurSldNum() > 1 ) ) } function HasNextSld() { return (GetCurSldNum() !=3D GetNumSlds()) } function CloseWindow() { if( HideMenu() ) return; =09 var event =3D PPTSld.event; if( !IsFramesMode() && event && (event.keyCode=3D=3D27 || event.keyCode=3D= =3D32 || event.type=3D=3D"click" ) ) window.close( self ); CatchNumKeys( self, event ); } function Unload() { gIsEndShow=3D0; } function SetupEndShow() { gIsEndShow=3D1; PPTSld.document.body.scroll=3D"no"; PPTSld.document.onkeypress=3DCloseWindow; PPTSld.document.onclick=3DCloseWindow; PPTSld.document.oncontextmenu=3D_CM; } function EndShow() { if( IsFramesMode() ) return if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue doc=3DPPTSld.document var dir =3D doc.body.dir if( dir !=3D "rtl" ) dir =3D "ltr"; doc.open() doc.writeln('


' + ENDSHOW_MESG + '

') doc.close() } function SetSldVisited(){ GetSldList().mList[gCurSld-1].mVisited=3Dtrue } function IsSldVisited(){ return GetSldList().mList[gCurSld-1].mVisited } function hrefList( sldHref, visible, advDelay, advClk ) { this.mSldHref=3D this.mNtsHref =3D sldHref this.mOrigVis=3D this.mVis =3D visible this.mVisited=3D false this.mAdvDelay=3D advDelay this.mAdvOnClk=3D advClk } function SldList(arr,curSld,fEnd) { this.mCurSld =3D curSld; this.mList =3D new Array(); var idx =3D 1; for(ii=3D0;ii 0) { PushSldList(sldList,fEnd); gCurSld =3D 1; } else if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue } function PushSldList(arr,fEnd) { var ii =3D gSldStack.length; gSldStack[ii] =3D new SldList(arr,gCurSld,fEnd); GoToSld( gSldStack[ii].mList[0].mSldHref ); } function PopSldList() { if (gSldStack[gSldStack.length-1].fEndShow) EndShow() else { gCurSld =3D gSldStack[gSldStack.length-1].mCurSld; gSldStack[gSldStack.length-1] =3D null; gSldStack.length--; var sldList =3D gSldStack[gSldStack.length-1]; GoToSld( sldList.mList[gCurSld - 1].mSldHref ); } } var custShowList=3Dnew Array(); /********************************************* Navigation button implementation There are 2 types of buttons: ImgBtn, TxtBtn implemented as function objects. They share a similiar interface so the event handlers can call SetActive, for example, on a button=20 object without needing to know exactly=20 what type of button it is. **********************************************/ //---------------------------------- function ImgBtn( oId,bId,w,action ) //---------------------------------- { var t=3Dthis t.Perform =3D _IBP t.SetActive =3D _IBSetA t.SetInactive=3D _IBSetI t.SetPressed =3D _IBSetP t.SetDisabled=3D _IBSetD t.Enabled =3D _IBSetE t.ChangeIcon =3D null t.UserAction =3D action t.ChgState =3D _IBUI t.mObjId =3D oId t.mBorderId=3D bId t.mWidth =3D w t.mIsOn =3D t.mCurState =3D 0 } function _IBSetA() { if( this.mIsOn ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _IBSetI() { if( this.mIsOn ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0=20 } } function _IBSetP() { if( this.mIsOn ) { obj=3Dthis.ChgState( gShadowClr,gHiliteClr,2 ) obj.style.posLeft+=3D1; obj.style.posTop+=3D1 } } function _IBSetD() { =20 obj=3Dthis.ChgState( gFaceClr,gFaceClr,0 ) obj.style.posTop=3D0=20 } function _IBSetE( state ) { var t=3Dthis GetObj( t.mBorderId ).style.visibility=3D"visible" if( state !=3D t.mIsOn ) { t.mIsOn=3Dstate if( state ) t.SetInactive() else t.SetDisabled() } } function _IBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( t.ChangeIcon ) { obj=3DGetObj(t.mObjId) if( t.ChangeIcon() ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-4)*t.mWidth else obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-0)*t.mWidth } t.SetActive() } =20 } function _IBUI( clr1,clr2,nextState ) { var t=3Dthis SetBorder( GetObj( t.mBorderId ),clr1,clr2 ) obj=3DGetObj( t.mObjId ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-nextState)*t.mWidth-obj= .style.posTop t.mCurState=3DnextState return obj } //----------------------------------------- function TxtBtn( oId,oeId,action,chkState ) //----------------------------------------- { var t=3Dthis t.Perform =3D _TBP t.SetActive =3D _TBSetA t.SetInactive=3D _TBSetI t.SetPressed =3D _TBSetP t.SetDisabled=3D _TBSetD t.SetEnabled =3D _TBSetE t.GetState =3D chkState t.UserAction =3D action t.ChgState =3D _TBUI t.mObjId =3D oId t.m_elementsId=3D oeId t.mIsOn =3D 1 } function _TBSetA() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gHiliteClr,gShadowClr,0,0 ) } function _TBSetI() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) } function _TBSetP() { if( this.mIsOn ) this.ChgState( gShadowClr,gHiliteClr,1,1 ) } function _TBSetD() { =20 this.ChgState( gFaceClr,gFaceClr,0,0 ) this.mIsOn =3D 0 } function _TBSetE() { var t=3Dthis if( !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) else t.ChgState( gShadowClr,gHiliteClr,1,1 ) t.mIsOn =3D 1 } function _TBP() { var t=3Dthis if( t.mIsOn ) {=20 if( t.UserAction !=3D null ) t.UserAction() if( !t.GetState ) return if( t.GetState() ) t.SetPressed() else t.SetActive() } =20 } function _TBUI( clr1,clr2,lOffset,tOffset ) { SetBorder( GetObj( this.mObjId ),clr1,clr2 ) Offset( GetObj( this.m_elementsId ),lOffset,tOffset ) } function Offset( obj, top, left ){ obj.style.top=3Dtop; obj.style.left=3Dle= ft } function SetBorder( obj, upperLeft, lowerRight ) { s=3Dobj.style; s.borderStyle =3D "solid" s.borderWidth =3D 1=20 s.borderLeftColor =3D s.borderTopColor =3D upperLeft s.borderBottomColor=3D s.borderRightColor =3D lowerRight } function GetBtnObj(){ return gBtnArr[window.event.srcElement.id] } function BtnOnOver(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetActive() } function BtnOnDown(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetPressed() } function BtnOnOut(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetInactive() } function BtnOnUp() { b=3DGetBtnObj() if( b !=3D null ) b.Perform() else Upd() } function GetNtsState(){ return parent.gNtsOpen } function GetOtlState(){ return parent.gOtlOpen } function GetOtlTxtState(){ return parent.gOtlTxtExp } function NtsBtnSetFlag( fVal ) { s=3Ddocument.all.item( this.m_flagId ).style s.display=3D"none" if( fVal ) s.display=3D"" else s.display=3D"none" } function _BSetA_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etActive() } function _BSetI_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etInactive() } function _BSetP_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etPressed() } function _BSetA_BorderImg() {=20 b =3D gBtnArr[this.mBorderId]=20 if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _BSetI_BorderImg() {=20 b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } var gHiliteClr=3D"THREEDHIGHLIGHT",gShadowClr=3D"THREEDSHADOW",gFaceClr=3D"= THREEDFACE" var gBtnArr =3D new Array() gBtnArr["nb_otl"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOtlPan= e,GetOtlState ) gBtnArr["nb_otlElem"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOt= lPane,GetOtlState ) gBtnArr["nb_nts"] =3D new ImgBtn( "nb_nts","nb_ntsBorder",10,parent.ToggleN= tsPane ) gBtnArr["nb_nts"].SetActive =3D _BSetA_BorderImg; gBtnArr["nb_nts"].SetInactive =3D _BSetI_BorderImg; gBtnArr["nb_ntsBorder"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.= ToggleNtsPane,GetNtsState ) gBtnArr["nb_ntsElem"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.To= ggleNtsPane,GetNtsState ) gBtnArr["nb_prevBorder"] =3D gBtnArr["nb_prev"]=3D new ImgBtn( "nb_prev","n= b_prevBorder",30,parent.GoToPrevSld ) gBtnArr["nb_nextBorder"] =3D gBtnArr["nb_next"]=3D new ImgBtn( "nb_next","n= b_nextBorder",30,parent.GoToNextSld ) gBtnArr["nb_sldshw"]=3D new ImgBtn( "nb_sldshw","nb_sldshwBorder",18,parent= .FullScreen ) gBtnArr["nb_sldshwBorder"] =3D new TxtBtn( "nb_sldshw","nb_sldshwBorder",pa= rent.FullScreen,null ) gBtnArr["nb_sldshwBorder"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwBorder"].SetInactive =3D _BSetI_Border; gBtnArr["nb_sldshwText"] =3D new TxtBtn( "nb_sldshw","nb_sldshwText",parent= .FullScreen,null ) gBtnArr["nb_sldshwText"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwText"].SetInactive =3D _BSetI_Border; gBtnArr["nb_voice"] =3D gBtnArr["nb_voiceBorder"] =3D new ImgBtn( "nb_voice= ","nb_voiceBorder",18,parent.ToggleVNarration ) gBtnArr["nb_otlTxtBorder"] =3D gBtnArr["nb_otlTxt"]=3D new ImgBtn( "nb_otlT= xt","nb_otlTxtBorder",23,parent.ToggleOtlText ) gBtnArr["nb_ntsBorder"].m_flagId=3D "nb_nts" gBtnArr["nb_ntsBorder"].SetFlag =3D NtsBtnSetFlag gBtnArr["nb_otlTxt"].ChangeIcon=3D GetOtlTxtState /********************************************* Context menu implementation _CM() is the function that's hooked up to the oncontextmenu event. Once we're asked to show the menu, we first build it by creating DIVs on-the-fly. Then we position it=20 within the screen area so it doesn't get clipped. Creating the DIVs using createElement() means we don't have to write out any extra HTML into the slide HTML files. **********************************************/ var sNext=3D"Next",sPrev=3D"Previous",sEnd=3D"End Show",sFont=3D"Arial",sAr= row=3D"Arrow",sFreeform=3D"Freeform",sRect=3D"Rectangle",sOval=3D"Oval" function ShowMenu() { BuildMenu(); var doc=3DPPTSld.document.body,x=3DPPTSld.event.clientX+doc.scrollLeft,y= =3DPPTSld.event.clientY+doc.scrollTop m =3D PPTSld.document.all.item("ctxtmenu") m.style.pixelLeft=3Dx if( (x+m.scrollWidth > doc.clientWidth)&&(x-m.scrollWidth > 0) ) m.style.pixelLeft=3Dx-m.scrollWidth m.style.pixelTop=3Dy if( (y+m.scrollHeight > doc.clientHeight)&&(y-m.scrollHeight > 0) ) m.style.pixelTop=3Dy-m.scrollHeight m.style.display=3D"" } function _CM() { if( !parent.IsFullScrMode() ) return; if(!PPTSld.event.ctrlKey) { ShowMenu() return false } else HideMenu() } function BuildMenu() { if( PPTSld.document.all.item("ctxtmenu") ) return var mObj=3DCreateItem( PPTSld.document.body ) mObj.id=3D"ctxtmenu" mObj.style.visibility=3D"hidden" var s=3DmObj.style s.position=3D"absolute" s.cursor=3D"default" s.width=3D"120px" SetCMBorder(mObj,"menu","black") var iObj=3DCreateItem( mObj ) SetCMBorder( iObj, "threedhighlight","threedshadow" ) iObj.style.padding=3D2 CreateMenuItem( iObj,sNext,M_GoNextSld,M_True ) CreateMenuItem( iObj,sPrev,M_GoPrevSld,M_HasPrevSld ) =09 CreateSeparator( iObj ) CreateMenuItem( iObj,sEnd,M_End,M_True ) mObj.style.visibility=3D"visible" } function Cancel() { window.event.cancelBubble=3Dtrue; window.event.returnVa= lue=3Dfalse } function Highlight() { ChangeClr("activecaption","threedhighlight") } function Deselect() { ChangeClr("threedface","menutext") } function Perform() { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) e.Action() else PPTSld.event.cancelBubble=3Dtrue } function ChangeClr( bg,clr ) { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) { e.style.backgroundColor=3Dbg e.style.color=3Dclr } } function M_HasPrevSld() { return( parent.HasPrevSld() ) } function M_GoNextSld() { if( gIsEndShow ) M_End(); else GoToNextSld() } function M_GoPrevSld() { if( gIsEndShow ) { gIsEndShow=3D0; history.back();= PPTSld.event.cancelBubble=3Dtrue; } else GoToPrevSld() } function M_True() { return true } function M_End() { window.close( self ) } function CreateMenuItem( node,text,action,eval ) { var e=3DCreateItem( node ) e.type=3D"menuitem" e.Action=3Daction e.IsActive=3Deval e.innerHTML=3Dtext if( !e.IsActive() ) e.style.color=3D"threedshadow" e.onclick=3DPerform e.onmouseover=3DHighlight e.onmouseout=3DDeselect s=3De.style; s.fontFamily=3DsFont s.fontSize=3D"9pt" s.paddingLeft=3D2 } function CreateSeparator( node ) { var sObj=3DCreateItem( node ) SetCMBorder(sObj,"menu","menu") var s=3DsObj.style s.borderTopColor=3D"threedshadow" s.borderBottomColor=3D"threedhighlight" s.height=3D1 s.fontSize=3D"0px" } function CreateItem( node ) { var elem=3DPPTSld.document.createElement("DIV") node.insertBefore( elem ) return elem } function SetCMBorder( o,ltClr,rbClr ) { var s=3Do.style s.backgroundColor=3D"menu" s.borderStyle=3D"solid" s.borderWidth=3D1 s.borderColor=3DltClr+" "+rbClr+" "+rbClr+" "+ltClr } ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/fullscreen.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/buttons.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhWAESAPf4AAAAAIAAAACAAICAAAAAgIAAgACAgICAgAQEBISEBASEBISEhAQEhMTExAQE /KTM9Pz8/ERERPz8BAT8/KSkpGRkhMTcxCRkxAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA AAAAAAAAAAAAAAAAAAAAAMDAwP8AAAD/AP//AAAA//8A/wD//////yH5BAEAAPgALAAAAABYARIA QAj/APEJHEiwoMGDCBMqXMiwocOHECNKnEixosWLGCEiQKCRo8YDIEHig2DxAD4LKD1avDDhgUuV GUOGbHBR5QGYFBG4fHAB58EKECJEwCfUYAWPFGAygLCRKQIIUKM6WAohKUGgCikcFWh1INWoYKVS 7SrQ41GbIhGYLAuVQVOoC+IyXUuUAkG1HE3KFDhAwkgJc5/qDZmxsOHDiBMrXsy4sePDGyP7lChT 5MULmDPnlDw5YmW6FTNrfgi0aNGEZPEtbfo2bNTUpYeeRph69dPWrqvCNFuBIGG1A59CYPAVQtwF cw0OxWdTIOiBCQAjaAB17fOFII8voGmRc+eOkilm/z9OvTtnjN4hYk1YoT3H2rnBOphPAB9skgq3 2lcaX/5YnJVt9BloAar12UEIRGCZdQghMABI1Tn32IQUVthYexhmqGGGMBHAgIfEhSiiiATAtOGJ GnYI4ogsEldicAYOGNJGZaml3Y0L3NTZUBz1xlB0PUoUI0jlVWRSVN89xBKSGB1YU1TMoRfVBEle hR9HQs1GEHxQ3RZZbveZthxt/LEmXHyp5XWABSCpaRJwbM13gAACPHVccgJFgF+NEhqUAEkQSCfc ddhVhh5dVTaEAEsTUNlkZUWKN9BNGDE6QU8OrSdbllzpxyVTTrU21Uj3scfhp7nNpyoDaTIEJ3P9 If8J2kbLNYegg9JRBwGhFvbq66+ZUiDssMQWK2yHxiZLrInKNotss8l+B5yBrr5p2UIJvortANoC 6+234IbLla/elRtZjeamh5CC3Sb0YLvixivvYkDFGlZqBNh7r4n6goVvv6/ZlCicN+kL71ALTnpQ dCIZp7CihkLA3UQmoWRBogyxtBPGCTnZncVR1rSTo5nuydC/Eo8kUH+lOoTyyvjoCuZu+PjYIKLD rZybtrM1d10C0QXKEVz48GrQkEeWdFJKlbb0UmEeV0SzyC6RvNB646LWIVjUNeC1zAFb+RDKXksM 9r531bwmpQW9+hQDDsx5pqwDRWBXcFES2hc+gEn/wJGdEEWdE6LoWcoxQweaTNmkhydkKaYMYY2Q p1unbLl/pPKbn3v7EZRvrKvqlja2ONvrtoIw9tn2g32/tQBlhtYkU+MNikZ7QYlPDPuMldpOmuJX nVo5VF3HjI+q89mteX5IDd/fVFClma5kiE4f2XUJhlz09gj2NbTDRifkmu7zXjR++RVJ/lPznuvr QH2iD6S+UewP9Dnon6d2NLwN8n90BB6hC68cFMCHoe+ACASP9c4DowUyEF0OPFcDI0ij/VXPaAKC UfhS95AKGoQ7IBRICI1HwhGaUIQoLGEKT6jCFrLwhSuMoQtlCMMZ2rCGOKShDm+4wxzy8Ic+DGIP B4cIRCKGMCAAOy== ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/frame.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons 3 Template ------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/outline.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii"
 No= tes
Slide Show
Outline
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------=_NextPart_01C5A279.34D0F860 Content-Location: file:///C:/CE525913/C-20Acids&Bases_files/filelist.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C5A279.34D0F860--