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Reaction Rates and Equilibrium<= /div>
TEKS: 2A, 2B, 2= C, 2D, 2E, 3B, 3C, 3D, 5A,  5B, 11B, 13C, 15A, 15B<= span style=3D'font-size:75%'>
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<= span style=3D'font-size:69%;color:black'>•Explain what is meant by the rate of a chemical reaction.
<= span style=3D'font-size:69%;color:black'>•Using collision theory, explain how the rate of a chemica= l reaction is influence by the reaction conditions.
<= span style=3D'font-size:69%;color:black'>•Predict changes in the equilibrium position due to change= s in concentration, temperature and pressure.
•Write the equilibrium-constant expression for a reaction = and calculate its value from experimen= tal data.
<= span style=3D'font-size:69%;color:black'>•Define entropy and free energy, and characterize <= /span>reactions as spontaneous or nonspontaneous.
•Describe how heat change and entropy change determine the spontaneity of a reaction.
•Calculate the standard entropy and free-energy changes that accompany chemical and physical processes.
<= span style=3D'font-size:69%;color:black'>•Interpret experimental rate data to deduce the rate laws = for simple chemical reactions.
<= span style=3D'font-size:69%;color:black'>•Given an energy diagram for a reaction, analyze the mechanism for the reaction.
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Collision Theory =
•Collision Theory – atoms, ions and molecules can react to form products when they c= ollide
------=_NextPart_01C5A261.5E4D2A50 Content-Location: file:///C:/06899145/C-19ReactionRate&Equilibriumwebpage_files/slide0006.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons
R= 26;Activation energy – the minimum = energy colliding parti= cles must have in order to react
R= 26;Activation complex – is the arrangement of atoms at the peak of the activation energy barrier
•Transition state – sometimes called the activated complex.
------=_NextPart_01C5A261.5E4D2A50 Content-Location: file:///C:/06899145/C-19ReactionRate&Equilibriumwebpage_files/slide0005.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Electrons
R= eaction progress 
3D"Text
Energy   <= /span>   
Reactant= s
Products=
Activa= ted Complex
Activation
Energy
Energy released by reaction
Energy of reactants
Energy of products
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Reaction Rates
R= 26;Effects of Temperature – Increase temperature incre= ases rate
R= 26;Effects of Concentration – Incre= ase concentration increases rate
•Effects of Particle Size – Decrease particle size increases rate
R= 26;Effects of Catalyst – Increases reaction rate both directions        equa= lly
•
<= span style=3D'font-size:75%;color:black;visibility:hidden'>•
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R= 26;Inhibitor – interferes with a catalyst
R= 26;Catalyst – does not affect the a= mount of reactants and products present at equilibrium
<= span style=3D'font-size:75%;color:black;visibility:hidden'>•
Inhibitor & Catalyst
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Reversible Reactions
R= 26;Reversible reactions – conversio= n of reactants into products and conversion= of products into reactants occur simultaneously
<= span style=3D'font-size:75%;color:black;visibility:hidden'>•
• 2SO2<= span style=3D'font-size:75%;color:black'> = ;  +   O2        = ;     2SO3
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Chemical Equilibrium
R= 26;Chemical Equilibrium – forward a= nd reverse reactions are taking place at the same rate
• A B
• 1% 99%
•
• A B
• 99% 1%
R= 26;LeChatelier’s Principle - If stress is applied to a sys= tem in dynamic equilibrium, the system cha= nges to relieve the = stress
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R= 26;#6&nb= sp; How is the equilibrium position of this reaction affected by the following changes? = ;
• C(s)   +   H2<= span style=3D'font-size:75%;color:black'>O(g)   +   heat        = ;         CO(g)   +H= 2(g)
• a. lowering the temperature = ;
• b. increasing the pressure
• c. remove H2
• d. add H2
•
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R= 26;#6&nb= sp; How is the equilibrium position of this reaction affected by the following changes? = ;
• C(s)   +   H2<= span style=3D'font-size:75%;color:black'>O(g)   +   heat        = ;         CO(g)   +H= 2(g)
• a. lowering the temperature
•        = ;   -shift left
• b. increasing the pressure =
•        = ;   -pressure adds stress to the side with the most of
•        = ;   gases – 1mol gas reactants, 2 mol gas product
•        = ;    shift left
• c. remove H2
•        = ;        -shift right
• d. add H2
•        = ;        -shift left=
•
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•#7&nb= sp; What effect does each change have on the equilibrium position of this reaction?=  
•N2(g)   +   3H2<= span style=3D'color:black'> (g)        = ;       2NH3(g)  +  92 kJ
a.addition of heat
b.increase pressure
c.addition of a catalyst
d.remove heat
e.add neon
f.increase volume
–↑ volume  ↓ pressure
–↓ volume   ↑ pressur= e
–
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•#7&nb= sp; What effect does each change have on the equilibrium position of this reaction?=  
•N2(g)   +   3H2<= span style=3D'color:black'> (g)        = ;       2NH3(g)  +  92 kJ
a.addition of heat – shift left
b.increase pressure – shift right
c.addition of a catalyst - nothing
d.remove heat – shift right (cool down)
e.add neon - nothing
f.increase volume – shift left
–↑ volume  ↓ pressure
–↓ volume   ↑ pressur= e
–
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Equilibrium Constant
– aA   +   bB        = ;          cC   +   dD
–
– Keq=  =3D   [C]c<= span style=3D'font-size:71%;color:black'> = ;  [D]d
–         = ;  [A]a   [B]b<= span style=3D'font-size:71%;color:black'>  
–
–
– Keq=  >  1 products favored at equilibrium
– Keq <  1 reactants favored at equilibrium
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R= 26;19&nb= sp; In which of these reactions are the products favored over the reactants?
R= 26;a. Keq  =3D  1 x 102
R= 26;b. Keq =3D  0.003
R= 26;c. Keq  =3D  3.5
<= span style=3D'font-size:75%;color:black'>•d. Keq=   =3D  6 x 10-4
<= span style=3D'font-size:75%;color:black;visibility:hidden'>•
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R= 26;19&nb= sp; In which of these reactions are the products favored over the reactants?
R= 26;a. Keq  =3D  1 x 102
•        = ;   - products favored
R= 26;b. Keq =3D  0.003
•        = ;   - reactants favored
<= span style=3D'font-size:75%;color:black'>•c. Keq=   =3D  3.5
•        = ;   - products favored
R= 26;d. Keq  =3D  6 x 10-4
•        = ;        - reactants favored
<= span style=3D'font-size:75%;color:black;visibility:hidden'>•
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<= /v:shape>
R= 26;#8&nb= sp; Analysis of an equilibrium mixture of nitrogen, = hydrogen and ammonia contained in a 1.= 0 L flask at 300C = gives the following results: hydrogen, 0.15 mol; nitrogen, 0.25 mol; ammonia, 0.10 mol.=   Calculate Keq
• N2(g)  +  3H2(g)        = ;    2NH3(g)
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<= /v:shape>
R= 26;#8&nb= sp; Analysis of an equilibrium mixture of nitrogen, hydrogen and ammonia contained in a 1.0 L flask at = 300C gives the following results: hydrogen, 0.15 mol; nitrogen, 0.25 mol; ammonia, 0.10 mol.  Calculate Keq
<= span style=3D'font-size:63%;color:black'>•R (reaction), I (initial amount), C (change), E (equilibrium conc.)
•    R N2(g)       +     3H2(g)        = ;       2NH3(g)
•    I 
•    C 
•    E    0.25 mol/L       0.15 mol/L      =     0.10 mol/L
•    Keq  =3D  [NH3]2
•        = ;       [N2] [H2]3
•    Keq =3D [0.10 mol/L]2        = ;            &n= bsp; =3D  11.85185  =3D  12 L2/mol2 =3D 12
•        = ;     [0.25 mol/L] [0.15 mol/L]3
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<= span style=3D'font-size:75%;color:black'>•#12 The decomposition of hydrogen iodide at 450°C in a 1.0 L container produces an equilibrium mixtures that contain 0.50 mol of hydrogen.  The equilibrium constant is 0.020 for the reaction.  How = many moles of iodine and of hydrogen iodide are present in the equilibrium mixture. =
•2HI(g)             H2 (g)   +   I2<= span style=3D'color:black'>(g)
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<= span style=3D'font-size:63%;color:black'>•#12 The decomposition of hydrogen iodide at 450°C in a 1.0 L container produces an equilibrium mixt= ures that contain 0.50 mol of hydrogen.  The equilibrium constant is 0.020 for the reaction.  How many moles of iodine and of hydrogen i= odide are present in the equilibrium mixture.
•  Keq =3D 0.020
•  R        2HI(g)    &nbs= p;         = ;   H2 (g)      +      I<= span style=3D'font-size:41%;color:black;position:relative;top:.37em;mso-text-ra= ise: -25%'>2(g)
• = ;  I
• = ;  C
• = ;  E         ? mol/L        = ;      0.50 mol/L    =   0.50 mol/L  (answer)&#= 13;
•  Keq  =3D 0.020 =3D [H2] [I2]       =3D=         = ;  [0.50 mol/L] [0.50 mol/L}
•        = ;            &n= bsp;       [HI]2        = ;            &n= bsp;            = ;  [HI]2
• = ;  [HI]2  =3D12.5
• = ;  [HI] =3D 3.53533 =3D 3.5 mol HI (answer)        = ;      
R= 26;
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<= span style=3D'font-size:75%;color:black'>•Sample Problem 19.3 p 546
• One mole of colorless hydrogen gas and one mole of violet iodine vapor are sealed in a 1.= 0 L flask and are allowed to react at 450°C. At equilibrium, 1.56 mol of colorless hydrogen iodide is present, together with some of the reactant gases.  Calculat= e Keq for the reaction.
• H= 2(g)   +   I2<= span style=3D'color:black'>(g)        = ;       2HI(g)
<= /div>
=
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= •Sample Problem 19.3 p 546 <= /span>
• One mole of colorless hydrogen gas and one mole of violet iodine vapor are sealed in a 1.0 L flask and = are allowed to react at 450°C. At equilibrium, 1.56 mol of colorless hydrogen iodide is present, together with some of the reactant gases.  Calculate Keq for the reaction.
• R   H2<= span style=3D'font-size:63%;color:black'>(g)        +     &nb= sp; I2(g)        = ;         2HI(g)
•     I    1mol/L        = ;       1 mol/L        = ;     0
•     C   0.78mol/L        = ;  0.78mol/L       1.56 mol/L
•     E   0.22 mol/L         0.22 mol/L       1.56 mol/L
• = ;  Keq  =3D  [HI]2        = ;           [1.56 mol/L]2    &nbs= p; =3D      50.28     =3D    50.&#= 13;
•        = ;      [H2] [I2]        = ;       [0.22] [0.22]
•        = ;       
•        = ;         
R= 26;
R= 26;
<= /div>
=
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Free Energy & Spontaneous Reactions
•Free energy – is the energy that is available to do work.
•Spontaneous reaction – reactions= known to produce products at specified conditions.
•Nonspontaneous reactions – do no= t give products under specified conditions.
•Entropy (S) – measure of disorde= r
•Law of Disorder – states that processes move in the direction of maximum disorder or randomness
–Entropy of a gas > liquid > soli= d
–Entropy increases when a substance is divided into parts
–Entropy tends to increase in chemical reactions in which the total number of product molecules is greater than the total <= /span>= number of reactant molecules
–Entropy tends to increase when tempera= ture increases as the temperature increases, the molecules move faster and faster, which increases the disorder.
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How Changes in Heat & Entropy Affect Reaction Spontaneity
• Heat Change Entropy <= /span>Spontaneous Reaction
•
• Decrease Increase Yes        = ;            &n= bsp;       (exot= hermic)
• Increase Increase= Only if unfavorable heat change (endothermic) is offset by favorable entropy        = ;           change
• Decrease Decrease = Only if unfavorable entropy (exothermic) change is offset by favorable heat change
• Increase Decrease No
• (endothermic)
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R= 26;Standard Heat of Formation Table 11.6 p 316
• ∆= H°   =3D   ∆H°(products)   -   ∆H°(reactants)= 3;
• <= /span> -∆H  =3D  exothermic
• +∆H  =3D endothermic
<= span style=3D'font-size:75%;color:black'>•Standard Entropies Table 19.2 p 558 =
• ∆S°   =3D   ∆S°(products)   -   ∆S°(reactants)= 3;
• <= /span>+∆S   =3D   exothermic
• -∆S   =3D  endothermic
•Standard Gibbs Free Energies of Formation Table= 19.4 p 563&= #13;
• ∆G°  =3D  ∆G°(products)  - ∆G°(reactants)
• <= /span> - ∆G  =3D  exothermic
• + ∆G  =3D  endothermic
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<= span style=3D'color:black'>•Spontaneous Reactions
• +∆S
• -∆H
• -∆G
= 226;
= 211;
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<= /v:shape>
R= 26;The standard entropies for some substa= nces at 25°C are
• KBrO3<= span style=3D'font-size:75%;color:black'>(s) ∆S° = ;  =3D   149.2 J/K·mol
• KBr(s) ∆S°       =3D=    96.4 J/K·mol=
• O2(g) ∆S°         =3D   205.0 J/K·mol
• Calculate ∆S° for t= he reaction
• KBrO3(s) →  <= /span>KBr(s)  +  3/2 O2(g)<= span style=3D'font-family:Garamond;mso-ascii-font-family:Garamond;mso-bidi-font= -family: Arial;font-size:75%;color:black;mso-special-format:lastCR;display:none'>&#= 13;
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<= /v:shape>
R= 26;The standard entropies for some substa= nces at 25°C are
• KBrO3<= span style=3D'font-size:63%;color:black'>(s) ∆S° = ;  =3D   149.2 J/K·mol
• KBr(s) ∆S°       =3D=    96.4 J/K·mol=
• O2(g) ∆S°         =3D   205.0 J/K·mol
• Calculate ∆S° for t= he reaction
• KBrO3(s) →  <= /span>KBr(s)  +  3/2 O2(g)
•     149.2        = ;    96.4        3/2(205.0)
•     ∆S°   =3D   ∆S°(products)   -   ∆S°(reactants)= 3;
•     ∆S°   =3D  <= /span>[96.4 + 3/2(205.0)] – [149.2]
•     ∆S°    =3D  [96.4 + 307.5] – [149.2]= 3;
•     ∆S°   =3D   403.9 -149.2
•     ∆S°   =3D   254.7 J/K
•    
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Free Energy Calculations
<= /v:shape>
<= span style=3D'font-size:75%;color:black'>•Gibbs Free-Energy change (∆= G°) is the maximum amount of energy that can be coupled to another proc= ess to do useful work.
• ∆G°  =3D  ∆G°(products)  - ∆G°(reactants)
• ∆G°  =3D  ∆H°  -  T∆S°
• Standard Gibbs Free Energies= Table 19.4 p 563
• ∆G&de= g; for elemental substances =3D 0  (important)
• The following two definition= s are not in your book
• Exergonic – spontaneous reactions that release free energy
• Endergonic – nonsponta= neous reactions that absorb free energy.
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<= span style=3D'font-size:75%;color:black'>•Sample Exercise 19.7 p 564
<= span style=3D'font-size:75%;color:black'>•Using values for ∆H and ∆S°= , determine whether this reaction is spontaneous at 25°C.
–∆G°  =3D  ∆H°  -  T∆S°
–C(s, graphite)  +  O2(g)  → CO2(g)
= 211;
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<= span style=3D'font-size:63%;color:black'>•Sample Exercise 19.7 p 564
<= span style=3D'font-size:63%;color:black'>•Using values for ∆H and ∆S°, determine whether this reaction is spontaneous at 25°C.
–∆G°  =3D  ∆H°  -  T∆S°
–        C(s, graphite)  +  O2(g)  → CO2(g)
–∆S°  1(5.694)        = ;  1(205.0)    &n= bsp; 1(213.6)
–∆H°  (0.0)        = ;        1(0.0)    &nbs= p;     1(-393.5)
–∆H°   =3D   ∆H°(products)   -   ∆H°(reactants)= 3;
–∆H°   =3D   -393.5 – [0.0 + 0.0]<= span style=3D'mso-spacerun:yes'>  =3D  -393.5 kJ
–∆S°   =3D   ∆S°(products)   -   ∆S°(reactants)= 3;
–∆S°   =3D   213.6 – [5.694 + 205.= 0] =3D 2.906  =3D 2.9 J/Kmol
–∆G°  =3D   ∆H°  -  T∆S°
–∆G°  =3D   -393.5 kJ – 298 K (2.= 9 x 10-3 kJ)
–∆G°  =3D   -393.5 – 0.8642  =3D  -394.36  =3D -394.4 kJ=
–∆G° is negative; therefore, it is spontaneous
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R= 26;#27 When gaseous nitrogen and hydrogen= are <= span style=3D'font-size:75%;color:black'>converted to gaseous ammonia, <= span style=3D'font-family:Arial;mso-bidi-font-family:Arial;font-size:75%;color:= black'>∆G° =3D -16.64 = kJ/mol.  Using the S° values in table 19.2 calculate = the ∆H°f for the formation of ammonia. =
• N2(g)  +  3H2(g)  →   2NH3(g)
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R= 26;#27 When gaseous nitrogen and hydrogen= are converted to gaseous ammonia, ∆G° =3D -16.64 kJ/mol.  Using the= S° values in table 19.2 calculate the ∆H°f for the formation of ammonia. =
• N2<= span style=3D'font-size:63%;color:black'>(g)&n= bsp; +  3H2(g)  →   2NH3(g)
•   ∆S°    1(191.5)  3(130.6)    2(192.5)
•   ∆S°  =3D   ∆S°(products)   -   ∆S°(reactants)= 3;
• = ;  ∆S°&= nbsp; =3D   2(192.5)  -  [191.5 + 3 (130.6) ]
•   ∆S°  =3D  385.0 – [583.3]   =3D  - 198.3 J/K for 2 mol NH3 formed
• = ;  Given ∆G°  =3D -16.64 kJ/mol =3D -33.28 kJ f= or 2 mol NH3
• = ;  ∆G° =3D  ∆H°  -  T∆S°
•   ∆H°  =3D  ∆G° +  T∆S°
• = ;  ∆H°  =3D  33.28 kJ  +  298(-198.3 x 10-3 kJ/mol
•   ∆H°<= span style=3D'mso-spacerun:yes'>  =3D  -92.373 kJ/2 mol =3D  = 92.4 kJ/2mol =3D -46.2 kJ/mol
•
•
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R= 26;#32a Determine whether the follow reac= tion is spon= taneous.  Assume all substances are at 25°C and 101.3 kPa.
• 2Na(s)  +  Cl2(g)   →  2NaCl(s)
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R= 26;#32a Determine whether the follow reac= tion is spontaneous.  Assume all substances are at 25= °C and 101.3 kPa.
• 2Na(s)  +  Cl2(g)   →  2NaCl(s)= 3;
• ∆G°      2(0.0)      1(0.0)        = ;  2(-384.03)
•∆G°  =3D   ∆G°(products)  - ∆G°(reactants)
•∆G°  =3D   2(-384.03) – [ 0.0 + 0.0]  =3D  768.06 kJ
•-∆G°=   =3D  spontaneous <= /span>
•
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Rate Laws
R= 26;Reaction Rate is the number of atoms, = ions or mole= cules that react in a given time to form products.
R= 26;Rate Law is an expression relating the= rate of react= ion to the concentration of reactants.
<= span style=3D'font-size:75%;color:black'>•Specific rate constant (k) is a proportionality constant relating the concentration of= the reactants to the rate of the reaction<= /span>
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Rate Laws
•A  →  B
•Rate  =3D  [∆A]   ;  ∆A     =3D   proportional to [A]
–         = ;  ∆t        = ;   ∆t
–Rate =3D  k x [A]a
R= 11;
–aA&nb= sp; +   bB  → cC   +   dD
–        = ;            &n= bsp;    order      order
–Rate   =3D   k[A]a   [B]b
–You can only make this assumption if y= ou are not given any d= ata except the equation.
= 211;
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R= 26;1st order reaction – the reactio= n rate is proportional to the concentration of only one reactant
̶= 6;#34 Suppose a first order reaction ini= tially proceeds at a = rate of 0.5 mol/L·sec.=   What will be the rate be <= /span>when half the starting material remains.  When one-fourth of the starting material remain= s.
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•1st order reaction – the reactio= n rate is proportional to the concentration of only one reactant
<= span style=3D'font-size:75%;color:black'>•#34 Suppose a first order reaction initially proceeds at a rate of 0.5 mol/L·sec.&= nbsp; What will be the rate be when half the starting material remains.  When one-fourth of the starting material remains.
•     Rate =3D 0.5 mol/Ls
•     Rate =3D 0.5 mo= l/Ls x .5 =3D 0.25 mol/Ls
•     Rate =3D 0.5 mo= l/Ls x .25 =3D 0.125 mol/Ls
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Reaction Mechanisms
R= 26;Elementary reaction – reactants = are converted to products in a simple set
R= 26;Reaction Mechanism – includes al= l the elementary react= ions of a complex reaction
R= 26;Intermediate – a product of a re= action that immediately becomes a reactant for another reaction
• N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  → = ;  N2   +   O        = ;            &n= bsp;    2 elementary steps
• N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  +   O   →   N2   +   O2        = ;            &n= bsp;   
• 2N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  →   2N2   +   O2<= span style=3D'font-size:75%;color:black;display:none'>
•
• What is the intermediate?
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Reaction Mechanisms
R= 26;Elementary reaction – reactants = are converted to products in a simple set
R= 26;Reaction Mechanism – includes al= l the elementary react= ions of a complex reaction
R= 26;Intermediate – a product of a re= action that immediately becomes a reactant for another reaction
• N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  → = ;  N2   +   O        = ;            &n= bsp;    2 elementary steps
• N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  +   O   →   N2   +   O2        = ;            &n= bsp;   
• 2N2<= span style=3D'font-size:75%;color:black'>O&nbs= p;  →   2N2   +   O2<= span style=3D'font-size:75%;color:black;display:none'>
•
• What is the intermediate?  O
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•#35&n= bsp; Ammonium ions and nitrite ions react in water to form nitrogen gas.&= nbsp; Determine the kinetic order of the reaction with respect to = NH4+, NO2- and the overall order of the reaction.
• NH4+   +   NO2<= span style=3D'font-size:41%;color:black;position:relative;top:-.45em;mso-text-r= aise: 30%'>-   →   N= 2   +   2H2<= span style=3D'font-size:63%;color:black'>O
• [NO2-] [NH4+] Rate
10.0100 0.200 <= /span>  5.4 x 10-7
20.0200 0.200 <= /span>10.8 x 10-7
30.0400 0.200 <= /span>21.5 x 10-7
40.0600 0.200 <= /span>32.3 x 10-7
50.200 0.0202 =         = ;     10.8 x 10-7
60.200 0.0404 =         = ;     21.6 x 10-7
70.200 0.0606 =         = ;     32.4 x 10-7
80.200 0.0808 =         = ;     43.3 x 10-7
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•<= /span>Calculations
•<= span style=3D'mso-tab-count:3;width:25.07%'> NH4+   +   NO2-   →   N2   +   2H2O
•
•<= span style=3D'mso-tab-count:1;width:8.35%'> [NO2-] [NH4+] Rate=
10.0100 0.200   5.4= x 10-7
20.0200 0.200 10.8 x 10-7
30.0400 0.200 21.5 x 10-7
40.0600 0.200 32.3 x 10-7
50.200 0.0202 10.8 x 10-7
60.200 0.0404 21.6 x 10-7
70.200 0.0606 32.4 x 10-7
80.200 0.0808 43.3 x 10-7
•
•        = ;          Rate     =3D     k [NO2-]x [NH4+]y
•        = ;          Rate     =3D     k [NO2-]x [NH4+]y
•Row = 2  =3D  10.8 x 10-7  =3D k [0.020]x [0.200]y
•Row = 1  =3D    5.4 x 10-7  =3D k [0.010]x [0.200]y
•        = ;            &n= bsp;         2x  =3D  2;  x =3D1 =
•        = ;            &n= bsp;   [NO2-]&nbs= p; =3D 1st order
•
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•<= /span>Calculations
•<= span style=3D'mso-tab-count:3;width:25.07%'> NH4+   +   NO2-   →   N2   +   2H2O
•
•<= span style=3D'mso-tab-count:1;width:8.35%'> [NO2-] [NH4+] Rate=
10.0100 0.200   5.4= x 10-7
20.0200 0.200 10.8 x 10-7
30.0400 0.200 21.5 x 10-7
40.0600 0.200 32.3 x 10-7
50.200 0.0202 10.8 x 10-7
60.200 0.0404 21.6 x 10-7
70.200 0.0606 32.4 x 10-7
80.200 0.0808 43.3 x 10-7
•
•        = ;          Rate     =3D     k [NO2-]x [NH4+]y
•        = ;          Rate     =3D     k [NO2-]x [NH4+]y
•Row = 6  =3D  21.6 x 10-7  =3D k [0.020]x [0.0404]y
•Row = 5  =3D  10.8 x 10-7  =3D k [0.020]x [0.0202]y
•        = ;            &n= bsp;         2y  =3D  2;  y =3D1 =
•        = ;            &n= bsp;   [NH4+]&nbs= p; =3D 1st order
•[NO<= /span>2-]  =3D 1st order ;  [NH4+]  =3D 1st order
•over= all order – add orders
•1 + = 1  =3D  2nd order overall
•
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•<= /span>Calculations:  Short Cut
•<= span style=3D'mso-tab-count:3;width:23.78%'> NH4+   +   NO2-   →   N2   +   2H2O
•
•<= span style=3D'mso-tab-count:1;width:7.92%'> [NO2-]x [NH4+]y R= ate
10.0100    2x 0.200        2   5.4 x 10-7
20.0200 0.200 <= /span>10.8 x 10-7
30.0400 0.200 21.5 x 10-7
40.0600 0.200 32.3 x 10-7
50.200 0.0202    2y        2 10.8 x 10-7
60.200 0.0404 21.6 x 10-7
70.200 0.0606 32.4 x 10-7
80.200 0.0808 43.3 x 10-7
<= span style=3D'font-size:63%;color:black;font-weight:bold;visibility:hidden'>9
•2= x  =3D  2 ; x  =3D 1 ; NO<= /span>2– is 1st=  order
•2= y  =3D  2;  y  =3D 1 ; NH4+ is 1st order
•O= verall order – add orders
• = 1 + 1 =3D 2 (2nd order overall)
•
• =
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application/javascript; charset="us-ascii" function LoadSld() { var sld=3DGetObj("SlideObj") if( !g_supportsPPTHTML ) { =09 sld.style.visibility=3D"visible" return } if( MakeNotesVis() ) return runAnimations =3D _InitAnimations(); =09 if( IsWin("PPTSld") ) parent.SldUpdated(GetSldId()) g_origSz=3DparseInt(SlideObj.style.fontSize) g_origH=3Dsld.style.posHeight g_origW=3Dsld.style.posWidth g_scaleHyperlinks=3D(document.all.tags("AREA").length>0) if( g_scaleHyperlinks ) InitHLinkArray() if( g_scaleInFrame||(IsWin("PPTSld") && parent.IsFullScrMode() ) ) document.body.scroll=3D"no" _RSW() if( IsWin("PPTSld") && parent.IsFullScrMode() ) FullScrInit(); =09 MakeSldVis(); ChkAutoAdv() if( runAnimations ) { if( document.all("NSPlay") ) document.all("NSPlay").autoStart =3D false; if( sld.filters && sld.filters.revealtrans ) setTimeout( "document.body.start()", sld.filters.revealtrans.duration * = 1000 ); else document.body.start(); } } function MakeSldVis()=20 { var fTrans=3Dg_showAnimation && SldHasTrans() if( fTrans )=09 { if( g_bgSound ) { idx=3Dg_bgSound.indexOf(","); pptSound.src=3Dg_bgSound.substr( 0, idx ); pptSound.loop=3D -(parseInt(g_bgSound.substr(idx+1))); } SlideObj.filters.revealtrans.Apply()=09 } SlideObj.style.visibility=3D"visible" if( fTrans ) SlideObj.filters.revealtrans.Play() } function MakeNotesVis()=20 { if( !IsNts() ) return false=20 SlideObj.style.display=3D"none" nObj =3D document.all.item("NotesObj") parent.SetHasNts(0) if( nObj ) {=20 nObj.style.display=3D"" parent.SetHasNts(1) } return 1 } function ChkAutoAdv() { if(SldHasTrans()) SlideObj.onfilterchange=3DAutoAdv else AutoAdv() } function AutoAdv() { if(!IsWin("PPTSld") || !gUseSldTimings )return var sld=3DGetCurSld() if( (sld.mAdvDelay>0) && !parent.IsFramesMode() ) setTimeout("parent.GoToNextSld()",sld.mAdvDelay) } function GetObj(id) { if(g_supportsPPTHTML) return document.all(id); else return document.getElementById(id); } function SldHasTrans() { return SlideObj.style.filter !=3D ""; } function GetSldId() { return sId=3Dlocation.href.substring(location.href.la= stIndexOf('/')+1) } function HideMenu() { if( frames["PPTSld"] && PPTSld.document.all.item("ctx= tmenu") && PPTSld.ctxtmenu.style.display!=3D"none" ) { PPTSld.ctxtmenu.styl= e.display=3D'none'; return true } return false } function IsWin( name ) { return window.name =3D=3D name } function IsNts() { return IsWin("PPTNts") } function IsSldOrNts() { return( IsWin("PPTSld")||IsWin("PPTNts") ) } function SupportsPPTAnimation() { return( navigator.platform =3D=3D "Win32"= && navigator.appVersion.indexOf("Windows")>0 ) } function SupportsPPTHTML() { var appVer=3Dnavigator.appVersion, msie=3DappVer.indexOf("MSIE "), ver=3D0 if( msie >=3D 0 ) ver=3DparseFloat( appVer.substring( msie+5, appVer.indexOf(";",msie) ) ) else ver=3DparseInt(appVer) return( ver >=3D 4 && msie >=3D 0 ) } function _RSW() { if( !g_supportsPPTHTML || IsNts() || ( !g_scaleInFrame && (!IsWin("PPTSld") || !parent.IsFullScrMode()) ) ) return var padding=3D0; if( IsWin("PPTSld") && parent.IsFramesMode() ) padding=3D6 cltWidth=3Ddocument.body.clientWidth-padding cltHeight=3Ddocument.body.clientHeight-padding factor=3D(1.0*cltWidth)/g_origW if( cltHeight < g_origH*factor ) factor=3D(1.0*cltHeight)/g_origH newSize =3D g_origSz * factor if( newSize < 1 ) newSize=3D1 s=3DSlideObj.style s.fontSize=3DnewSize+"px" s.posWidth=3Dg_origW*factor s.posHeight=3Dg_origH*factor s.posLeft=3D(cltWidth-s.posWidth+padding)/2 s.posTop=3D(cltHeight-s.posHeight+padding)/2 if( g_scaleHyperlinks ) ScaleHyperlinks( factor ) } function _InitAnimations() { animRuntimeInstalled =3D ''+document.body.localTime !=3D 'undefined'; isFullScreen =3D (window.name =3D=3D "PPTSld") && !parent.IsFramesMode(); g_animUseRuntime =3D g_showAnimation && animRuntimeInstalled && !(isFullSc= reen && parent.IsSldVisited()); if( g_animUseRuntime ) { collSeq =3D document.all.tags("seq"); if( collSeq !=3D null ) { for(ii=3D0;ii numSlds ) gSldJumpIdx =3D numSlds; if ( gSldJumpIdx >=3D 0 ) { if ( gSldJumpIdx =3D=3D 0 ) gSldJumpIdx =3D 1; var jumpTo =3D parseInt(gSldJumpIdx); gSldJump =3D 0; gSldJumpIdx =3D ""; win.GoToSld( parent.GetSldList().mList[jumpTo-1].mSldHref ) } } } function _KDH() { if( event.keyCode =3D=3D 8 ) { event.returnValue =3D 0; parent.GoToPrevSld(); } } var g_HLinkArray =3D new Array(); =20 function IMapAreaObj( areaObj, coords ) { this.areaObj =3D areaObj; this.coords =3D coords; } function InitHLinkArray() { var appVer =3D navigator.appVersion; var msie =3D appVer.indexOf ( "MSIE " ) var ver =3D 0; if ( msie >=3D 0 ) ver =3D parseInt ( appVer.substring( msie+5 ) ); linkNum =3D 0; for (i=3D0; i 4 ) ) g_HLinkArray[linkNum++] =3D new IMapAreaObj( areaObj, ParseCoords( ar= eaObj.coords ) ); } } function ScaleHyperlinks( factor ) { =20 for ( ii=3D0; ii< g_HLinkArray.length; ii++) { coordsStr=3D""; imaObj =3D g_HLinkArray[ii]; for ( jj=3D0; jj < imaObj.coords.length-1; jj++ ) coordsStr +=3D (imaObj.coords[jj]*factor) + ","; coordsStr +=3D (imaObj.coords[jj]*factor); imaObj.areaObj.coords =3D coordsStr; } } function ParseCoords( coordsStr ) { var numArray =3D new Array(); var i =3D curPos =3D commaPos =3D 0; while ( ( commaPos =3D coordsStr.indexOf(",", curPos) ) !=3D -1 ) {=20 numArray[i++] =3D parseInt( coordsStr.substr( curPos, commaPos ) ); curPos =3D commaPos + 1; } numArray[i] =3D parseInt( coordsStr.substr( curPos ) ); return numArray; } function PlaySound( href, loop ){ href=3D unescape(href); if( window.event ) window.event.cancelBubble =3D true; pptSound.src =3D href; pptSound.loop =3D loop ? -1 : 0; } function DocumentOnClick() { if( IsNts() || parent.HideMenu() ) return; if( ( g_allowAdvOnClick && (window.name=3D=3D"PPTSld") && !parent.IsFrames= Mode() ) || (event && event.keyCode=3D=3D32) ) { =09 if( g_animUseRuntime && g_animMainSequence && g_animMainSequence.cangonex= t ) return; parent.GoToNextSld(); } } var g_supportsPPTHTML =3D SupportsPPTHTML(), g_scaleInFrame =3D 1, gId=3D""= , g_bgSound=3D"", g_scaleHyperlinks =3D false, g_allowAdvOnClick =3D 1, g_showInBrowser = =3D 0, gLoopCont =3D 0, gUseSldTimings =3D 0; var g_showAnimation =3D g_supportsPPTHTML && SupportsPPTAnimation() && ( (w= indow.name=3D=3D"PPTSld" && !parent.IsFramesMode()) || g_showInBrowser );va= r g_animManager =3D null; var g_animUseRuntime =3D false; var g_animItemsToHide, g_animInteractiveItems, g_animSlideTime; var g_animMainSequence =3D null; var ENDSHOW_MESG=3D"End of slide show, click to exit.", SCREEN_MODE=3D"Fram= es", gIsEndShow=3D0, NUM_VIS_SLDS=3D45, SCRIPT_HREF=3D"script.js", FULLSCR_= HREF=3D"fullscreen.htm"; var gCurSld =3D gPrevSld =3D 1, g_offset =3D 0, gNtsOpen =3D gHasNts =3D gO= tlTxtExp =3D 0, gHasNarration =3D 0, gOtlOpen =3D true window.gPPTHTML=3DSupportsPPTHTML() var gMainDoc=3Dnew Array(new hrefList("slide0001.htm",1,1573,1),new hrefLis= t("slide0034.htm",1,-1,1),new hrefList("slide0002.htm",1,-1,1),new hrefList= ("slide0006.htm",1,-1,1),new hrefList("slide0005.htm",1,-1,1),new hrefList(= "slide0007.htm",1,-1,1),new hrefList("slide0008.htm",1,-1,1),new hrefList("= slide0003.htm",1,-1,1),new hrefList("slide0009.htm",1,-1,1),new hrefList("s= lide0010.htm",1,-1,1),new hrefList("slide0035.htm",1,-1,1),new hrefList("sl= ide0011.htm",1,-1,1),new hrefList("slide0036.htm",1,-1,1),new hrefList("sli= de0012.htm",1,-1,1),new hrefList("slide0014.htm",1,-1,1),new hrefList("slid= e0037.htm",1,-1,1),new hrefList("slide0015.htm",1,-1,1),new hrefList("slide= 0038.htm",1,-1,1),new hrefList("slide0016.htm",1,-1,1),new hrefList("slide0= 039.htm",1,-1,1),new hrefList("slide0013.htm",1,-1,1),new hrefList("slide00= 40.htm",1,-1,1),new hrefList("slide0017.htm",1,-1,1),new hrefList("slide001= 8.htm",1,-1,1),new hrefList("slide0019.htm",1,-1,1),new hrefList("slide0020= .htm",1,-1,1),new hrefList("slide0021.htm",1,-1,1),new hrefList("slide0041.= htm",1,-1,1),new hrefList("slide0022.htm",1,-1,1),new hrefList("slide0026.h= tm",1,-1,1),new hrefList("slide0042.htm",1,-1,1),new hrefList("slide0027.ht= m",1,-1,1),new hrefList("slide0043.htm",1,-1,1),new hrefList("slide0028.htm= ",1,-1,1),new hrefList("slide0044.htm",1,-1,1),new hrefList("slide0029.htm"= ,1,-1,1),new hrefList("slide0030.htm",1,-1,1),new hrefList("slide0023.htm",= 1,-1,1),new hrefList("slide0045.htm",1,-1,1),new hrefList("slide0024.htm",1= ,-1,1),new hrefList("slide0046.htm",1,-1,1),new hrefList("slide0025.htm",1,= -1,1),new hrefList("slide0032.htm",1,-1,1),new hrefList("slide0047.htm",1,-= 1,1),new hrefList("slide0031.htm",1,-1,1)); /********************************************* Frameset functions These functions control slide navigation and state of the frameset. **********************************************/ function FullScrInit() { g_allowAdvOnClick =3D GetCurSld().mAdvOnClk document.body.style.backgroundColor=3D"black" document.oncontextmenu=3Dparent._CM; document.onkeydown =3D _KDH; document.ondragstart=3DCancel document.onselectstart=3DCancel self.focus() } function Redirect( frmId ) {=09 var str=3Ddocument.location.hash,idx=3Dstr.indexOf('#'), sId=3DGetSldId() if(idx>=3D0) str=3Dstr.substr(1); if( window.name !=3D frmId && ( sId !=3D str) ) { obj =3D GetObj("Main-File") window.location.href=3Dobj.href+"#"+sId return 1 } return 0 } var MHTMLPrefix =3D CalculateMHTMLPrefix();=20 function CalculateMHTMLPrefix() { if ( document.location.protocol =3D=3D 'mhtml:') {=20 href=3Dnew String(document.location.href)=20 Start=3Dhref.indexOf('!')+1=20 End=3Dhref.lastIndexOf('/')+1=20 if (End < Start)=20 return href.substring(0, Start)=20 else=20 return href.substring(0, End)=20 } return ''; } function GetTags(base,tag) { if(g_supportsPPTHTML) return base.all.tags(tag); else return base.getElementsByTagName(tag); } function UpdNtsPane(){ if(frames["PPTNts"]) PPTNts.location.replace( MHTMLP= refix+GetHrefObj( gCurSld ).mNtsHref ) } function UpdNavPane( sldIndex ){ if(gNavLoaded) PPTNav.UpdNav() } function UpdOtNavPane(){ if(gOtlNavLoaded) PPTOtlNav.UpdOtlNav() } function UpdOtlPane(){ if(gOtlLoaded) PPTOtl.UpdOtl() } function SetHasNts( fVal ) { if( gHasNts !=3D fVal ) { gHasNts=3DfVal UpdNavPane() } } function ToggleOtlText() { gOtlTxtExp=3D!gOtlTxtExp UpdOtlPane() } function ClearMedia() { // Clear any sounds playing before launching another browser window. Other= wise, // in fullscreen mode, you'll continue to hear the sound in the frames mod= e. if (PPTSld.pptSound) PPTSld.pptSound.loop =3D 0; } function FullScreen() {=20 if ( PPTSld.g_animUseRuntime ) PPTSld.document.body.pause(); ClearMedia(); var href =3D ( document.location.protocol =3D=3D 'mhtml:') ? FULLSCR_HREF = : FULLSCR_HREF+"#"+GetHrefObj(gCurSld).mSldHref; if(PPTNav.event.ctrlKey) { var w =3D (window.screen.availWidth * 1.0) / 2.0 var h =3D w * (PPTSld.g_origH * 1.0) / PPTSld.g_origW win =3D window.open( MHTMLPrefix+href,null,"toolbar=3D0,resizable=3D1,top= =3D0,left=3D0," + "width=3D"+ w + ",height=3D" + h ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } else { win =3D window.open( MHTMLPrefix+href,null,"fullscreen=3Dyes" ); if( win.document.body && PPTSld.g_animUseRuntime ) win.document.body.PPTSldFrameset=3Dwindow; } } function ToggleVNarration() { rObj=3DPPTSld.document.all("NSPlay") if( rObj && !PPTSld.g_animUseRuntime ) { if( (rObj.playState =3D=3D 1)||(rObj.playState =3D=3D 0) ) rObj.Play() else if( rObj.playState =3D=3D 2 ) rObj.Pause() else return; } else if( PPTSld.g_animUseRuntime ) { narObj =3D PPTSld.document.all("narrationID") if( narObj ) narObj.togglePause() } } function GetCurSldNum() { =20 obj=3DGetHrefObj(gCurSld) if( obj.mOrigVis =3D=3D 1 ) return obj.mSldIdx else =20 return gCurSld } function GetNumSlds() { =20 if( GetHrefObj(gCurSld).mOrigVis =3D=3D 1 ) return GetSldList().mNumVisSlds; else return GetSldList().mList.length } function GetSldNum( href ) { for(ii=3D0; ii 1 ) PopSldList(); else if( !IsFramesMode() ) { if( gLoopCont ) GoToFirst() else EndShow() } } function GoToPrevSld() { ii=3DgCurSld-1 if( ii > 0 ) { obj=3DGetHrefObj(ii) while ( obj && ( obj.mVis =3D=3D 0 ) && ( ii>0 ) ) obj=3DGetHrefObj(--ii) if( ii =3D=3D 0 ) ii=3D1 GoToSldNum(ii) } } function GoToFirst(){ GoToSld( GetHrefObj(1).mSldHref ) } function GoToLast() { ii=3DGetSldList().mList.length if( ii !=3D gCurSld ) GoToSld( GetHrefObj(ii).mSldHref ) } function GoToSldNum( num ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue obj =3D GetHrefObj( num ) obj.mVis=3D1 gPrevSld=3DgCurSld gCurSld =3D num; PPTSld.location.replace(MHTMLPrefix+obj.mSldHref) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function GoToSld( href ) { if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue GetHrefObj( GetSldNum(href) ).mVis=3D1 PPTSld.location.replace(MHTMLPrefix+href) } function SldUpdated( id ) { if( id =3D=3D GetHrefObj(gCurSld).mSldHref ) return gPrevSld=3DgCurSld gCurSld=3DGetSldNum(id) if( IsFramesMode() ) { UpdNavPane(); UpdOtlPane(); UpdNtsPane() } } function PrevSldViewed(){ GoToSld( GetHrefObj(gPrevSld).mSldHref ) } function HasPrevSld() { return ( gIsEndShow || ( gCurSld !=3D 1 && GetHrefO= bj( gCurSld-1 ).mVis =3D=3D 1 )||( GetCurSldNum() > 1 ) ) } function HasNextSld() { return (GetCurSldNum() !=3D GetNumSlds()) } function CloseWindow() { if( HideMenu() ) return; =09 var event =3D PPTSld.event; if( !IsFramesMode() && event && (event.keyCode=3D=3D27 || event.keyCode=3D= =3D32 || event.type=3D=3D"click" ) ) window.close( self ); CatchNumKeys( self, event ); } function Unload() { gIsEndShow=3D0; } function SetupEndShow() { gIsEndShow=3D1; PPTSld.document.body.scroll=3D"no"; PPTSld.document.onkeypress=3DCloseWindow; PPTSld.document.onclick=3DCloseWindow; PPTSld.document.oncontextmenu=3D_CM; } function EndShow() { if( IsFramesMode() ) return if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue doc=3DPPTSld.document var dir =3D doc.body.dir if( dir !=3D "rtl" ) dir =3D "ltr"; doc.open() doc.writeln('


' + ENDSHOW_MESG + '

') doc.close() } function SetSldVisited(){ GetSldList().mList[gCurSld-1].mVisited=3Dtrue } function IsSldVisited(){ return GetSldList().mList[gCurSld-1].mVisited } function hrefList( sldHref, visible, advDelay, advClk ) { this.mSldHref=3D this.mNtsHref =3D sldHref this.mOrigVis=3D this.mVis =3D visible this.mVisited=3D false this.mAdvDelay=3D advDelay this.mAdvOnClk=3D advClk } function SldList(arr,curSld,fEnd) { this.mCurSld =3D curSld; this.mList =3D new Array(); var idx =3D 1; for(ii=3D0;ii 0) { PushSldList(sldList,fEnd); gCurSld =3D 1; } else if( PPTSld.event ) PPTSld.event.cancelBubble=3Dtrue } function PushSldList(arr,fEnd) { var ii =3D gSldStack.length; gSldStack[ii] =3D new SldList(arr,gCurSld,fEnd); GoToSld( gSldStack[ii].mList[0].mSldHref ); } function PopSldList() { if (gSldStack[gSldStack.length-1].fEndShow) EndShow() else { gCurSld =3D gSldStack[gSldStack.length-1].mCurSld; gSldStack[gSldStack.length-1] =3D null; gSldStack.length--; var sldList =3D gSldStack[gSldStack.length-1]; GoToSld( sldList.mList[gCurSld - 1].mSldHref ); } } var custShowList=3Dnew Array(); /********************************************* Navigation button implementation There are 2 types of buttons: ImgBtn, TxtBtn implemented as function objects. They share a similiar interface so the event handlers can call SetActive, for example, on a button=20 object without needing to know exactly=20 what type of button it is. **********************************************/ //---------------------------------- function ImgBtn( oId,bId,w,action ) //---------------------------------- { var t=3Dthis t.Perform =3D _IBP t.SetActive =3D _IBSetA t.SetInactive=3D _IBSetI t.SetPressed =3D _IBSetP t.SetDisabled=3D _IBSetD t.Enabled =3D _IBSetE t.ChangeIcon =3D null t.UserAction =3D action t.ChgState =3D _IBUI t.mObjId =3D oId t.mBorderId=3D bId t.mWidth =3D w t.mIsOn =3D t.mCurState =3D 0 } function _IBSetA() { if( this.mIsOn ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _IBSetI() { if( this.mIsOn ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0=20 } } function _IBSetP() { if( this.mIsOn ) { obj=3Dthis.ChgState( gShadowClr,gHiliteClr,2 ) obj.style.posLeft+=3D1; obj.style.posTop+=3D1 } } function _IBSetD() { =20 obj=3Dthis.ChgState( gFaceClr,gFaceClr,0 ) obj.style.posTop=3D0=20 } function _IBSetE( state ) { var t=3Dthis GetObj( t.mBorderId ).style.visibility=3D"visible" if( state !=3D t.mIsOn ) { t.mIsOn=3Dstate if( state ) t.SetInactive() else t.SetDisabled() } } function _IBP() { var t=3Dthis if( t.mIsOn ) { if( t.UserAction !=3D null ) t.UserAction() if( t.ChangeIcon ) { obj=3DGetObj(t.mObjId) if( t.ChangeIcon() ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-4)*t.mWidth else obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-0)*t.mWidth } t.SetActive() } =20 } function _IBUI( clr1,clr2,nextState ) { var t=3Dthis SetBorder( GetObj( t.mBorderId ),clr1,clr2 ) obj=3DGetObj( t.mObjId ) obj.style.posLeft=3Dobj.style.posLeft+(t.mCurState-nextState)*t.mWidth-obj= .style.posTop t.mCurState=3DnextState return obj } //----------------------------------------- function TxtBtn( oId,oeId,action,chkState ) //----------------------------------------- { var t=3Dthis t.Perform =3D _TBP t.SetActive =3D _TBSetA t.SetInactive=3D _TBSetI t.SetPressed =3D _TBSetP t.SetDisabled=3D _TBSetD t.SetEnabled =3D _TBSetE t.GetState =3D chkState t.UserAction =3D action t.ChgState =3D _TBUI t.mObjId =3D oId t.m_elementsId=3D oeId t.mIsOn =3D 1 } function _TBSetA() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gHiliteClr,gShadowClr,0,0 ) } function _TBSetI() { var t=3Dthis if( t.mIsOn && !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) } function _TBSetP() { if( this.mIsOn ) this.ChgState( gShadowClr,gHiliteClr,1,1 ) } function _TBSetD() { =20 this.ChgState( gFaceClr,gFaceClr,0,0 ) this.mIsOn =3D 0 } function _TBSetE() { var t=3Dthis if( !t.GetState() ) t.ChgState( gFaceClr,gFaceClr,0,0 ) else t.ChgState( gShadowClr,gHiliteClr,1,1 ) t.mIsOn =3D 1 } function _TBP() { var t=3Dthis if( t.mIsOn ) {=20 if( t.UserAction !=3D null ) t.UserAction() if( !t.GetState ) return if( t.GetState() ) t.SetPressed() else t.SetActive() } =20 } function _TBUI( clr1,clr2,lOffset,tOffset ) { SetBorder( GetObj( this.mObjId ),clr1,clr2 ) Offset( GetObj( this.m_elementsId ),lOffset,tOffset ) } function Offset( obj, top, left ){ obj.style.top=3Dtop; obj.style.left=3Dle= ft } function SetBorder( obj, upperLeft, lowerRight ) { s=3Dobj.style; s.borderStyle =3D "solid" s.borderWidth =3D 1=20 s.borderLeftColor =3D s.borderTopColor =3D upperLeft s.borderBottomColor=3D s.borderRightColor =3D lowerRight } function GetBtnObj(){ return gBtnArr[window.event.srcElement.id] } function BtnOnOver(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetActive() } function BtnOnDown(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetPressed() } function BtnOnOut(){ b=3DGetBtnObj(); if( b !=3D null ) b.SetInactive() } function BtnOnUp() { b=3DGetBtnObj() if( b !=3D null ) b.Perform() else Upd() } function GetNtsState(){ return parent.gNtsOpen } function GetOtlState(){ return parent.gOtlOpen } function GetOtlTxtState(){ return parent.gOtlTxtExp } function NtsBtnSetFlag( fVal ) { s=3Ddocument.all.item( this.m_flagId ).style s.display=3D"none" if( fVal ) s.display=3D"" else s.display=3D"none" } function _BSetA_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etActive() } function _BSetI_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etInactive() } function _BSetP_Border(){ b =3D gBtnArr[this.mObjId]; if( b !=3D null ) b.S= etPressed() } function _BSetA_BorderImg() {=20 b =3D gBtnArr[this.mBorderId]=20 if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gHiliteClr,gShadowClr,2 ) obj.style.posTop=3D0 } } function _BSetI_BorderImg() {=20 b =3D gBtnArr[this.mBorderId] if( b !=3D null && this.mIsOn && !b.GetState() ) { obj=3Dthis.ChgState( gFaceClr,gFaceClr,1 ) obj.style.posTop=3D0 } } var gHiliteClr=3D"THREEDHIGHLIGHT",gShadowClr=3D"THREEDSHADOW",gFaceClr=3D"= THREEDFACE" var gBtnArr =3D new Array() gBtnArr["nb_otl"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOtlPan= e,GetOtlState ) gBtnArr["nb_otlElem"] =3D new TxtBtn( "nb_otl","nb_otlElem",parent.ToggleOt= lPane,GetOtlState ) gBtnArr["nb_nts"] =3D new ImgBtn( "nb_nts","nb_ntsBorder",10,parent.ToggleN= tsPane ) gBtnArr["nb_nts"].SetActive =3D _BSetA_BorderImg; gBtnArr["nb_nts"].SetInactive =3D _BSetI_BorderImg; gBtnArr["nb_ntsBorder"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.= ToggleNtsPane,GetNtsState ) gBtnArr["nb_ntsElem"] =3D new TxtBtn( "nb_ntsBorder","nb_ntsElem",parent.To= ggleNtsPane,GetNtsState ) gBtnArr["nb_prevBorder"] =3D gBtnArr["nb_prev"]=3D new ImgBtn( "nb_prev","n= b_prevBorder",30,parent.GoToPrevSld ) gBtnArr["nb_nextBorder"] =3D gBtnArr["nb_next"]=3D new ImgBtn( "nb_next","n= b_nextBorder",30,parent.GoToNextSld ) gBtnArr["nb_sldshw"]=3D new ImgBtn( "nb_sldshw","nb_sldshwBorder",18,parent= .FullScreen ) gBtnArr["nb_sldshwBorder"] =3D new TxtBtn( "nb_sldshw","nb_sldshwBorder",pa= rent.FullScreen,null ) gBtnArr["nb_sldshwBorder"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwBorder"].SetInactive =3D _BSetI_Border; gBtnArr["nb_sldshwText"] =3D new TxtBtn( "nb_sldshw","nb_sldshwText",parent= .FullScreen,null ) gBtnArr["nb_sldshwText"].SetActive =3D _BSetA_Border; gBtnArr["nb_sldshwText"].SetInactive =3D _BSetI_Border; gBtnArr["nb_voice"] =3D gBtnArr["nb_voiceBorder"] =3D new ImgBtn( "nb_voice= ","nb_voiceBorder",18,parent.ToggleVNarration ) gBtnArr["nb_otlTxtBorder"] =3D gBtnArr["nb_otlTxt"]=3D new ImgBtn( "nb_otlT= xt","nb_otlTxtBorder",23,parent.ToggleOtlText ) gBtnArr["nb_ntsBorder"].m_flagId=3D "nb_nts" gBtnArr["nb_ntsBorder"].SetFlag =3D NtsBtnSetFlag gBtnArr["nb_otlTxt"].ChangeIcon=3D GetOtlTxtState /********************************************* Context menu implementation _CM() is the function that's hooked up to the oncontextmenu event. Once we're asked to show the menu, we first build it by creating DIVs on-the-fly. Then we position it=20 within the screen area so it doesn't get clipped. Creating the DIVs using createElement() means we don't have to write out any extra HTML into the slide HTML files. **********************************************/ var sNext=3D"Next",sPrev=3D"Previous",sEnd=3D"End Show",sFont=3D"Arial",sAr= row=3D"Arrow",sFreeform=3D"Freeform",sRect=3D"Rectangle",sOval=3D"Oval" function ShowMenu() { BuildMenu(); var doc=3DPPTSld.document.body,x=3DPPTSld.event.clientX+doc.scrollLeft,y= =3DPPTSld.event.clientY+doc.scrollTop m =3D PPTSld.document.all.item("ctxtmenu") m.style.pixelLeft=3Dx if( (x+m.scrollWidth > doc.clientWidth)&&(x-m.scrollWidth > 0) ) m.style.pixelLeft=3Dx-m.scrollWidth m.style.pixelTop=3Dy if( (y+m.scrollHeight > doc.clientHeight)&&(y-m.scrollHeight > 0) ) m.style.pixelTop=3Dy-m.scrollHeight m.style.display=3D"" } function _CM() { if( !parent.IsFullScrMode() ) return; if(!PPTSld.event.ctrlKey) { ShowMenu() return false } else HideMenu() } function BuildMenu() { if( PPTSld.document.all.item("ctxtmenu") ) return var mObj=3DCreateItem( PPTSld.document.body ) mObj.id=3D"ctxtmenu" mObj.style.visibility=3D"hidden" var s=3DmObj.style s.position=3D"absolute" s.cursor=3D"default" s.width=3D"120px" SetCMBorder(mObj,"menu","black") var iObj=3DCreateItem( mObj ) SetCMBorder( iObj, "threedhighlight","threedshadow" ) iObj.style.padding=3D2 CreateMenuItem( iObj,sNext,M_GoNextSld,M_True ) CreateMenuItem( iObj,sPrev,M_GoPrevSld,M_HasPrevSld ) =09 CreateSeparator( iObj ) CreateMenuItem( iObj,sEnd,M_End,M_True ) mObj.style.visibility=3D"visible" } function Cancel() { window.event.cancelBubble=3Dtrue; window.event.returnVa= lue=3Dfalse } function Highlight() { ChangeClr("activecaption","threedhighlight") } function Deselect() { ChangeClr("threedface","menutext") } function Perform() { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) e.Action() else PPTSld.event.cancelBubble=3Dtrue } function ChangeClr( bg,clr ) { e=3DPPTSld.event.srcElement if( e.type=3D=3D"menuitem" && e.IsActive() ) { e.style.backgroundColor=3Dbg e.style.color=3Dclr } } function M_HasPrevSld() { return( parent.HasPrevSld() ) } function M_GoNextSld() { if( gIsEndShow ) M_End(); else GoToNextSld() } function M_GoPrevSld() { if( gIsEndShow ) { gIsEndShow=3D0; history.back();= PPTSld.event.cancelBubble=3Dtrue; } else GoToPrevSld() } function M_True() { return true } function M_End() { window.close( self ) } function CreateMenuItem( node,text,action,eval ) { var e=3DCreateItem( node ) e.type=3D"menuitem" e.Action=3Daction e.IsActive=3Deval e.innerHTML=3Dtext if( !e.IsActive() ) e.style.color=3D"threedshadow" e.onclick=3DPerform e.onmouseover=3DHighlight e.onmouseout=3DDeselect s=3De.style; 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charset="us-ascii" Electrons ------=_NextPart_01C5A261.5E4D2A50 Content-Location: file:///C:/06899145/C-19ReactionRate&Equilibriumwebpage_files/outline.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii"
 No= tes
Slide Show
Outline
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------=_NextPart_01C5A261.5E4D2A50 Content-Location: file:///C:/06899145/C-19ReactionRate&Equilibriumwebpage_files/filelist.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C5A261.5E4D2A50--